Halogenated Ti3C2 MXenes with Electrochemically Active Terminals for High-Performance Zinc Ion Batteries
文献类型：期刊论文
| 作者 | Li, Mian; Li, Xinliang; Qin, Guifang; Luo, Kan; Lu, Jun; Li, Youbing; Liang, Guojin; Huang, Zhaodong; Zhou, Jie; Hultman, Lars |
| 刊名 | ACS NANO
 |
| 出版日期 | 2021 |
| 卷号 | 15期号:1页码:1077-1085 |
| 关键词 | GENERALIZED GRADIENT APPROXIMATION TRANSITION-METAL CARBIDES ELECTRONIC-PROPERTIES SURFACE-STRUCTURE INTERCALATION SOLIDS ANODE |
| 英文摘要 | The class of two-dimensional metal carbides and nitrides known as MXenes offer a distinct manner of property tailoring for a wide range of applications. The ability to tune the surface chemistry for expanding the property space of MXenes is thus an important topic, although experimental exploration of surface terminals remains a challenge. Here, we synthesized Ti3C2 MXene with unitary, binary, and ternary halogen terminals, e.g., -Cl, -Br, -I, -BrI, and -ClBrI, to investigate the effect of surface chemistry on the properties of MXenes. The electrochemical activity of Br and I elements results in the extraordinary electrochemical performance of the MXenes as cathodes for aqueous zinc ion batteries. The -Br- and -I-containing MXenes, e.g., Ti3C2Br2 and Ti3C2I2, exhibit distinct discharge platforms with considerable capacities of 97.6 and 135 mA.g(-1). Ti3C2 (BrI) and Ti3C2 (ClBrI) exhibit dual discharge platforms with capacities of 117.2 and 106.7 mAh.g(-1). In contrast, the previously discovered MXenes Ti3C2Cl2 and Ti3C2 (OF) exhibit no discharge platforms and only similar to 50% of capacities and energy densities of Ti3C2Br2. These results emphasize the effectiveness of the Lewis-acidic-melt etching route for tuning the surface chemistry of MXenes and also show promise for expanding the MXene family toward various applications. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/22259]  |
| 专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
| 作者单位 | 1.Huang, Q (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Engn Lab Adv Energy Mat, Ningbo 315201, Zhejiang, Peoples R China. 2.Huang, Q (corresponding author), Qianwan Inst CNiTECH, Hangzhou Bay Dist, Ningbo 315336, Zhejiang, Peoples R China. 3.Zhi, CY (corresponding author), City Univ Hong Kong, Dept Mat Sci & Engn, Kowloon, Hong Kong 999077, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Li, Mian,Li, Xinliang,Qin, Guifang,et al. Halogenated Ti3C2 MXenes with Electrochemically Active Terminals for High-Performance Zinc Ion Batteries[J]. ACS NANO,2021,15(1):1077-1085. |
| APA | Li, Mian.,Li, Xinliang.,Qin, Guifang.,Luo, Kan.,Lu, Jun.,...&Huang, Qing.(2021).Halogenated Ti3C2 MXenes with Electrochemically Active Terminals for High-Performance Zinc Ion Batteries.ACS NANO,15(1),1077-1085. |
| MLA | Li, Mian,et al."Halogenated Ti3C2 MXenes with Electrochemically Active Terminals for High-Performance Zinc Ion Batteries".ACS NANO 15.1(2021):1077-1085. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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