Efficiently optimizing the oxygen catalytic properties of the birnessite type manganese dioxide for zinc-air batteries
文献类型：期刊论文
| 作者 | Chen, Bin; Miao, He; Hu, Ruigan; Yin, Mingming; Wu, Xuyang; Sun, Shanshan; Wang, Qin; Li, Shihua; Yuan, Jinliang |
| 刊名 | JOURNAL OF ALLOYS AND COMPOUNDS
 |
| 出版日期 | 2021 |
| 卷号 | 852 |
| 关键词 | REDUCTION REACTION BIFUNCTIONAL ELECTROCATALYSTS HIGHLY EFFICIENT GRAPHENE SHEETS DOPED MNO2 EVOLUTION PERFORMANCE COBALT CARBON CONSTRUCTION |
| 英文摘要 | It is of great significance to design and develop the high-efficiency and low-cost bifunctional oxygen catalysts. Manganese dioxide (MnO2) is one of the most widely studied catalysts for oxygen reduction reaction (ORR) on account of the high reserves and environmental friendliness. Whereas, the catalytic activity of MnO2 for oxygen evolution reaction (OER) is so inferior that it cannot be used as the bifunctional oxygen catalysts. In this work, the assembled nanospheres of cobalt ion intercalated birnessite type MnO2 with a unique lamellar structure are synthesized by a very facile one-step liquid-phase method under mild conditions. Importantly, compared with the pristine MnO2, the optimized cobalt ion intercalated delta-MnO2 (24Co-MnO2) shows the greatly enhanced OER catalytic activity and stability. Specially, 24Co-MnO(2 )displays a low OER overpotential of 430 mV at 10 mA cm(-2) in 0.1 M KOH. In addition, 24Co-MnO2 shows much higher bifunctional oxygen catalytic activity than most of the manganese oxide based catalysts. Moreover, 24Co-MnO2 as the bifunctional oxygen catalyst is assembled in the aqueous and flexible solid-state zinc-air batteries (ZABs), showing the high peak power density and outstanding cycling stability. (C) 2020 Elsevier B.V. All rights reserved. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/22262]  |
| 专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
| 作者单位 | 1.Yuan, JL (corresponding author), Ningbo Univ, Fac Maritime & Transportat, Ningbo 315211, Peoples R China. 2.Miao, H |
| 推荐引用方式 GB/T 7714 | Chen, Bin,Miao, He,Hu, Ruigan,et al. Efficiently optimizing the oxygen catalytic properties of the birnessite type manganese dioxide for zinc-air batteries[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2021,852. |
| APA | Chen, Bin.,Miao, He.,Hu, Ruigan.,Yin, Mingming.,Wu, Xuyang.,...&Yuan, Jinliang.(2021).Efficiently optimizing the oxygen catalytic properties of the birnessite type manganese dioxide for zinc-air batteries.JOURNAL OF ALLOYS AND COMPOUNDS,852. |
| MLA | Chen, Bin,et al."Efficiently optimizing the oxygen catalytic properties of the birnessite type manganese dioxide for zinc-air batteries".JOURNAL OF ALLOYS AND COMPOUNDS 852(2021). |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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