Potassium Ions Induced Framework Interpenetration for Enhancing the Stability of Uranium-Based Porphyrin MOF with Visible-Light-Driven Photocatalytic Activity
文献类型：期刊论文
| 作者 | Huang, Zhi-Wei; Hu, Kong-Qiu; Mei, Lei; Wang, Cong-Zhi; Chen, Yan-Mei; Wu, Wang-Suo; Chai, Zhi-Fang; Shi, Wei-Qun |
| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2021 |
| 卷号 | 60期号:2页码:652-660 |
| 关键词 | METAL-ORGANIC FRAMEWORK SEGMENTED CONTRACTION SCHEME RATIONAL DESIGN STYRENE OXIDE CO2 CYCLOADDITION OXIDATION CATALYSTS INSIGHTS CLUSTERS |
| 英文摘要 | The stability of many MOFs is not satisfactory, which severely limits the exploration of their potential applications. Given this, we have proposed a strategy to improve the stability of MOFs by introducing alkali metal K+ capable of coordinating with metal nodes, which finally induces the interpenetrating uranyl-porphyrin framework to connect as a whole (IHEP-9). The stability experiments reveal that the IHEP-9 has good thermal stability up to 400 degrees C and can maintain its crystalline state in the aqueous solution with pH ranging from 2 to 11. The catalytic activity of IHEP-9 as a heterogeneous photocatalyst for CO2 cycloaddition under the driving of visible light at room temperature is also demonstrated. This induced interpenetration and fixation method may be promising for the fabrication of more functional MOFs with improved structural stability. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/22278]  |
| 专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
| 作者单位 | 1.Shi, WQ (corresponding author), Chinese Acad Sci, Inst High Energy Phys, Lab Nucl Energy Chem, Beijing 100049, Peoples R China. 2.Mei, L |
| 推荐引用方式 GB/T 7714 | Huang, Zhi-Wei,Hu, Kong-Qiu,Mei, Lei,et al. Potassium Ions Induced Framework Interpenetration for Enhancing the Stability of Uranium-Based Porphyrin MOF with Visible-Light-Driven Photocatalytic Activity[J]. INORGANIC CHEMISTRY,2021,60(2):652-660. |
| APA | Huang, Zhi-Wei.,Hu, Kong-Qiu.,Mei, Lei.,Wang, Cong-Zhi.,Chen, Yan-Mei.,...&Shi, Wei-Qun.(2021).Potassium Ions Induced Framework Interpenetration for Enhancing the Stability of Uranium-Based Porphyrin MOF with Visible-Light-Driven Photocatalytic Activity.INORGANIC CHEMISTRY,60(2),652-660. |
| MLA | Huang, Zhi-Wei,et al."Potassium Ions Induced Framework Interpenetration for Enhancing the Stability of Uranium-Based Porphyrin MOF with Visible-Light-Driven Photocatalytic Activity".INORGANIC CHEMISTRY 60.2(2021):652-660. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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