Multifunctional Polyhedral Oligomeric Silsesquioxane (POSS) Based Hybrid Porous Materials for CO2 Uptake and Iodine Adsorption
文献类型：期刊论文
| 作者 | Gamal Mohamed, Mohamed; Tsai, Mei-Yin; Wang, Chih-Feng; Huang, Chih-Feng; Danko, Martin; Dai, Lizong; Chen, Tao; Kuo, Shiao-Wei |
| 刊名 | POLYMERS
 |
| 出版日期 | 2021 |
| 卷号 | 13期号:2 |
| 英文摘要 | In this study, two different types of hybrid porous organic polymers (POPs), polyhedral oligomeric silsesquioxane tetraphenylpyrazine (POSS-TPP) and tetraphenylethene (POSS-TPE), were successfully synthesized through the Friedel-Crafts polymerization of tetraphenylpyrazine (TPP) and tetraphenylethene (TPE), respectively, with octavinylsilsesquioxane (OVS) as node building blocks, in the presence of anhydrous FeCl3 as a catalyst and 1,2-dichloroethane at 60 degrees C. Based on N-2 adsorption and thermogravimetric analyses, the resulting hybrid porous materials displayed high surface areas (270 m(2)/g for POSS-TPP and 741 m(2)/g for POSS-TPE) and outstanding thermal stabilities. Furthermore, as-prepared POSS-TPP exhibited a high carbon dioxide capacity (1.63 mmol/g at 298 K and 2.88 mmol/g at 273 K) with an excellent high adsorption capacity for iodine, reaching up to 363 mg/g, compared with the POSS-TPE (309 mg/g). |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/22329]  |
| 专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
| 作者单位 | 1.Kuo, SW (corresponding author), Kaohsiung Med Univ, Dept Med & Appl Chem, Kaohsiung 807, Taiwan. 2.Kuo, SW (corresponding author), Natl Sun Yat Sen Univ, Ctr Crystal Res, Dept Mat & Optoelect Sci, Kaohsiung 80424, Taiwan. |
| 推荐引用方式 GB/T 7714 | Gamal Mohamed, Mohamed,Tsai, Mei-Yin,Wang, Chih-Feng,et al. Multifunctional Polyhedral Oligomeric Silsesquioxane (POSS) Based Hybrid Porous Materials for CO2 Uptake and Iodine Adsorption[J]. POLYMERS,2021,13(2). |
| APA | Gamal Mohamed, Mohamed.,Tsai, Mei-Yin.,Wang, Chih-Feng.,Huang, Chih-Feng.,Danko, Martin.,...&Kuo, Shiao-Wei.(2021).Multifunctional Polyhedral Oligomeric Silsesquioxane (POSS) Based Hybrid Porous Materials for CO2 Uptake and Iodine Adsorption.POLYMERS,13(2). |
| MLA | Gamal Mohamed, Mohamed,et al."Multifunctional Polyhedral Oligomeric Silsesquioxane (POSS) Based Hybrid Porous Materials for CO2 Uptake and Iodine Adsorption".POLYMERS 13.2(2021). |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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