A Probable Origin of Dibenzothiophenes in Coals and Oils
文献类型：期刊论文
| 作者 | Ji, Yu; Yao, Qiang; Cao, Weihong; Zhao, Yueying |
| 刊名 | ENERGIES
 |
| 出版日期 | 2021 |
| 卷号 | 14期号:1 |
| 关键词 | ORGANIC SULFUR-COMPOUNDS CRUDE OILS AROMATIC-HYDROCARBONS MODEL COMPOUNDS PETROLEUM PYROLYSIS IDENTIFICATION INDICATORS DEPRESSION BIOMASS |
| 英文摘要 | To probe the possibility of thiophenolate as an origin of dibenzothiophenes (DBTs) and establish the detailed chemical transformations from thiophenolate to DBTs, the thermal degradation of thiophenolate has been carried out at various temperatures. The characterizations of both gaseous products and solid residues indicate that DBTs together with benzene, diphenyl sulfide, and diphenyl disulfide are the major degradation products. The presence of benzene supports that the thermal degradation of thiophenolate begins with the homolysis of Ar-H bonds. The subsequent hydroarylation followed by the elimination and cyclization reactions facilely generates DBTs. The transformation of thiophenolate to DBTs is chemically simple and highly geochemically feasible. It readily unifies the chemical pathways involved in the generation of DBTs from thiophenolate and that of dibenzofurans from phenolate in nature. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/22340]  |
| 专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
| 作者单位 | 1.Yao, Q (corresponding author), Key Lab Biobased Polymer Mat Technol & Applicat Z, Ningbo 315201, Peoples R China. 2.Yao, Q (corresponding author), Univ Chinese Acad Sci, Sch Chem Sci, Beijing 100049, Peoples R China. 3.Yao, Q (corresponding author), Chinese Acad Sci, Ningbo Key Lab Polymer Mat, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Ji, Yu,Yao, Qiang,Cao, Weihong,et al. A Probable Origin of Dibenzothiophenes in Coals and Oils[J]. ENERGIES,2021,14(1). |
| APA | Ji, Yu,Yao, Qiang,Cao, Weihong,&Zhao, Yueying.(2021).A Probable Origin of Dibenzothiophenes in Coals and Oils.ENERGIES,14(1). |
| MLA | Ji, Yu,et al."A Probable Origin of Dibenzothiophenes in Coals and Oils".ENERGIES 14.1(2021). |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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