High-loading lateral Li deposition realized by a Scalable Fluorocarbon Bonded Laminates
文献类型：期刊论文
| 作者 | Ren, Feihong; Li, Zhendong; Huai, Liyuan; Ren, Zhongmin; Wang, Muqin; Liu, Jian; Lin, Huan; Peng, Zhe; Wang, Deyu |
| 刊名 | CARBON
 |
| 出版日期 | 2021 |
| 卷号 | 171页码:894-906 |
| 英文摘要 | High-energy-density lithium (Li) metal batteries (LMBs) have been intensely revisited in recent years due to the urgent need of advanced energy storage technologies. However, a step towards the practical application of LMBs is still plagued by the lack of scalable method for Li metal protection. Rationally designed carbon nanostructures have been employed to stabilize Li metal anode, but only demonstrated as model structures without scalable productions. Herein, a type of fluorocarbon (-CFx) bonded carbon nanoparticles is developed, which not only exhibit much better manoeuvrability to form uniform and crack-free laminates as large-area Li protective structure, but the presence of -CFx also leads to the formation of a high-content lithium fluoride (LiF) interphase via a lithiation route, endowing high-loading lateral Li deposition by the increase of interfacial energy between the substrate and the highly fluorinated interphase. Based on the efficacious Li protection by the -CFx bonded carbon laminates, a stable cycling of 300 cycles is achieved for Li parallel to LiNi0.88Co0.09Al0.03O2 (NCA) full cell with a high NCA loading of 5 mAh cm(-2). These results demonstrate that protecting high-loading Li metal anodes in the practical LMBs is feasible by the functional carbon synthesized from our easy-scalable method. (C) 2020 Elsevier Ltd. All rights reserved. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/22347]  |
| 专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
| 作者单位 | 1.Peng, Z (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China. 2.Wang, DY (corresponding author), Jianghan Univ, Sch Chem & Environm Engn, Key Lab Optoelect Chem Mat & Devices, Wuhan 430056, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Ren, Feihong,Li, Zhendong,Huai, Liyuan,et al. High-loading lateral Li deposition realized by a Scalable Fluorocarbon Bonded Laminates[J]. CARBON,2021,171:894-906. |
| APA | Ren, Feihong.,Li, Zhendong.,Huai, Liyuan.,Ren, Zhongmin.,Wang, Muqin.,...&Wang, Deyu.(2021).High-loading lateral Li deposition realized by a Scalable Fluorocarbon Bonded Laminates.CARBON,171,894-906. |
| MLA | Ren, Feihong,et al."High-loading lateral Li deposition realized by a Scalable Fluorocarbon Bonded Laminates".CARBON 171(2021):894-906. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。