Naphthalene diimide based polymer as electron transport layer in inverted perovskite solar cells
文献类型：期刊论文
| 作者 | Deng, Changbo; Wan, Li; Li, Shuang; Tao, Lupiao; Wang, Su-nan; Zhang, Wenjun; Fang, Junfeng; Fu, Zhengping; Song, Weijie |
| 刊名 | ORGANIC ELECTRONICS
 |
| 出版日期 | 2020 |
| 卷号 | 87 |
| 关键词 | HIGHLY EFFICIENT STABILITY |
| 英文摘要 | The solution-processable electron transport layer (ETL) is essential for the electron transport and extraction of inverted perovskite solar cells (PSCs). A new naphthalene diimide based copolymer with phosphite ester pendants (PFNDI) is developed as an ETL in inverted PSCs. The naphthalene diimide backbone and the phosphite ester pendants endow PFNDI a good electron transport property and a strong binding force on perovskite. By introducing PFNDI on the perovskite interface, we succeed in improving surface morphologies of perovskite film, reducing the trap density and facilitating electron transport properties. The PFNDI-based devices exhibit an optimal power conversion efficiency of 18.25% (with the V-OC = 1.068 V, J(SC) = 22.53 mA cm(-2) and FF = 75.85%) and fine long-term stabilities. The un-encapsulated PFNDI-based devices maintain 80% of their initial performance after storage for more than 500 h at 20 degrees C in air with a relative humidity of 25% and 75% of their initial efficiency after continuously heating for about 300 h. Our work demonstrated that NDI-based polymers with proper pendant groups can be the ideal n-type organic materials for high-performance PSCs. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/22420]  |
| 专题 | 中国科学院宁波材料技术与工程研究所 2020专题_期刊论文 2021专题_期刊论文 |
| 作者单位 | 1.Fang, JF (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China. 2.Zhang, WJ |
| 推荐引用方式 GB/T 7714 | Deng, Changbo,Wan, Li,Li, Shuang,et al. Naphthalene diimide based polymer as electron transport layer in inverted perovskite solar cells[J]. ORGANIC ELECTRONICS,2020,87. |
| APA | Deng, Changbo.,Wan, Li.,Li, Shuang.,Tao, Lupiao.,Wang, Su-nan.,...&Song, Weijie.(2020).Naphthalene diimide based polymer as electron transport layer in inverted perovskite solar cells.ORGANIC ELECTRONICS,87. |
| MLA | Deng, Changbo,et al."Naphthalene diimide based polymer as electron transport layer in inverted perovskite solar cells".ORGANIC ELECTRONICS 87(2020). |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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