Reduced Graphene Oxide Modified Few-Layer Exfoliated Graphite to Enhance the Stability of the Negative Electrode of a Graphite-Based Potassium Ion Battery
文献类型：期刊论文
| 作者 | Wang, Jian; Yin, Bo; Gao, Tian; Wang, Xingyi; Li, Wang; Hong, Xingxing; Wang, Zhuqing; He, Haiyong |
| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 2022 |
| 卷号 | 38期号:2 |
| 关键词 | ANODE MATERIALS CARBON |
| 英文摘要 | The intercalation of potassium in graphite provides high energy density owing to the low potential of 0.24 V vs. K/K+, thereby making it a promising anode material for potassium ion batteries. However, the high volume expansion (60%) of graphite after potassium intercalation induces significant stress and electrode pulverization. Additionally, the sluggish kinetics of potassium insertion undermine the rate capability of electrodes. Using few-layer exfoliated graphite (EG) as a negative electrode material effectively relieves expansion-induced stress. Unfortunately, the close stacking of ultra-thin two-dimensional EG impedes ion transport. Furthermore, EG with smooth surfaces lacks sites to adsorb K+, which is unfavorable for intercalation reactions. To address these problems, in this study, we designed an rGO/EG/rGO sandwich that coats EG with reduced graphene oxide (rGO). This complex material has two main advantages: (1) its 3D network can effectively prevent EG from stacking and buffer the volumetric variation of EG to improve the cyclic stability of the electrode, and (2) the loose structure and rich functional groups of rGO can also enhance the kinetic of potassium intercalation. Through hydrothermal reduction, GO was coated onto the EG surface and cross-linked to form a 3D network, by which EG stacking could be effectively mitigated. The rGO : EG ratio was precisely controlled by modulating the amount of reactant GO and EG. Transmission electron microscopy and scanning electron microscopy images showed that the rGO was uniformly coated on the EG surface to form a sandwich structure. X-ray diffraction patterns and Raman spectra demonstrated that rGO was physically adsorbed on the EG surface without notable chemical interactions. The EG structure was retained to ensure that its characteristic electrochemical properties were unaffected. Cyclic voltammetry and galvanostatic cycling tests were performed on the complex material with various rGO : EG ratios, exhibiting that rGO : EG = 1 : 1 (w/w) was optimal with a specific capacity of 443 mAh.g(-1) at 50 mAg(-1). Even when operated at a high current density of 800 mA.g(-1), a specific capacity of 190 mAh.g(-1) was achieved, retaining 42.9% of the low-rate capacity, far exceeding those of pristine EG (14.2%) and rGO (27.2%). These results demonstrate that the rGO coating indeed enhanced the kinetics of potassium intercalation and efficiently improved the capacity and rate capability compared to pristine EG. We hope this work sheds light on novel approaches to improving potassium intercalation mechanisms in graphite. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/21230]  |
| 专题 | 2021专题_期刊论文 2022专题_期刊论文 |
| 作者单位 | 1.He, HY (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Inst New Energy Technol, Ningbo 315201, Zhejiang, Peoples R China. 2.Wang, ZQ (corresponding author), Anqing Normal Univ, Coll Chem & Chem Engn, Anqing 246002, Anhui, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Wang, Jian,Yin, Bo,Gao, Tian,et al. Reduced Graphene Oxide Modified Few-Layer Exfoliated Graphite to Enhance the Stability of the Negative Electrode of a Graphite-Based Potassium Ion Battery[J]. ACTA PHYSICO-CHIMICA SINICA,2022,38(2). |
| APA | Wang, Jian.,Yin, Bo.,Gao, Tian.,Wang, Xingyi.,Li, Wang.,...&He, Haiyong.(2022).Reduced Graphene Oxide Modified Few-Layer Exfoliated Graphite to Enhance the Stability of the Negative Electrode of a Graphite-Based Potassium Ion Battery.ACTA PHYSICO-CHIMICA SINICA,38(2). |
| MLA | Wang, Jian,et al."Reduced Graphene Oxide Modified Few-Layer Exfoliated Graphite to Enhance the Stability of the Negative Electrode of a Graphite-Based Potassium Ion Battery".ACTA PHYSICO-CHIMICA SINICA 38.2(2022). |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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