2,5-Bis(hydroxymethyl)furan: A new alternative to HMF for simultaneously electrocatalytic production of FDCA and H-2 over CoOOH/Ni electrodes
文献类型：期刊论文
| 作者 | Zhu, Bin; Chen, Chunlin; Huai, Liyuan; Zhou, Zhenqiang; Wang, Lei; Zhang, Jian |
| 刊名 | APPLIED CATALYSIS B-ENVIRONMENTAL
 |
| 出版日期 | 2021 |
| 卷号 | 297 |
| 关键词 | ELECTROCHEMICAL OXIDATION HYDROGENATION COBALT PD CATALYSTS GRAPHENE ACID AU |
| 英文摘要 | Simultaneous production of value-added 2,5-furandicarboxylic acid (FDCA) and H-2 from the integrated 5-hydroxymethylfurfural (HMF) oxidation and hydrogen evolution reaction by electrocatalysis has drawn tremendous attention due to the significantly improved energy efficiency. However, HMF is not thermally and chemically stable enough to often cause heavy degradation, impeding its storage and industrialization. In this work, a more stable furan molecule, 2,5-bis(hydroxymethyl)furan (BHMF), was employed as the reaction substrate into the coupling system for the first time. By means of facile electrodeposition and subsequent oxidative activation, the standing CoOOH nanosheet electrocatalyst was fabricated to realize a complete BHMF conversion with 90.2 % FDCA yield and 100 % current efficiency for H-2 evolution. The reaction path and apparent activation energies were therefore discussed. Scalable properties and electrochemical durability of CoOOH were evaluated in a continuous flow reactor to harvest gram-level solid FDCA, highlighting the prospect of green coupling electrolysis for industrial application. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/21313]  |
| 专题 | 2021专题_期刊论文 |
| 作者单位 | 1.Chen, CL 2.Zhang, J (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, 1219 Zhongguan West Rd, Ningbo 315201, Zhejiang, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Zhu, Bin,Chen, Chunlin,Huai, Liyuan,et al. 2,5-Bis(hydroxymethyl)furan: A new alternative to HMF for simultaneously electrocatalytic production of FDCA and H-2 over CoOOH/Ni electrodes[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2021,297. |
| APA | Zhu, Bin,Chen, Chunlin,Huai, Liyuan,Zhou, Zhenqiang,Wang, Lei,&Zhang, Jian.(2021).2,5-Bis(hydroxymethyl)furan: A new alternative to HMF for simultaneously electrocatalytic production of FDCA and H-2 over CoOOH/Ni electrodes.APPLIED CATALYSIS B-ENVIRONMENTAL,297. |
| MLA | Zhu, Bin,et al."2,5-Bis(hydroxymethyl)furan: A new alternative to HMF for simultaneously electrocatalytic production of FDCA and H-2 over CoOOH/Ni electrodes".APPLIED CATALYSIS B-ENVIRONMENTAL 297(2021). |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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