A Self-Healing and Ionic Liquid Affiliative Polyurethane toward a Piezo 2 Protein Inspired Ionic Skin
文献类型:期刊论文
作者 | Chen, Chao; Ying, Wu Bin; Li, Jiayi; Kong, Zhengyang; Li, Fenglong; Hu, Han; Tian, Ying; Kim, Do Hwan; Zhang, Ruoyu; Zhu, Jin |
刊名 | ADVANCED FUNCTIONAL MATERIALS
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出版日期 | 2021 |
关键词 | SHAPE-MEMORY SENSORS |
英文摘要 | Ionic skin (I-Skin) has the advantage of feasible compatibility with biological systems. Nevertheless, developing a stable and durable ionic skin is challenging. Here, an ionic polyurethane (i-PU) is synthesized, which is capable of self-healing and able to lock the ionic liquids (ILs). In detail, an ionic chain extender containing an ammonium cationic group is synthesized, followed by the polymerization to obtain the target i-PU. Through electrostatic interaction and chain diffusion, the i-PU can be fully self-healed at room temperature within 400 min. Afterward, low contact angle (37 degrees) of the i-PU against IL and the density functional theory (DFT) calculation prove their good compatibility and strong interaction, originating from the electrostatic interaction. The Raman intensity map shows the reversible process of the enrichment and restoration of ionic concentration on the i-PU/IL surface when external pressure is applied or released, proving stable binding of ions by ionic polymer chains. Lastly, the self-healing I-Skin based on the i-PU/IL is fabricated with a wide range of pressures (0-120 kPa), fast response time (32 ms), excellent antifatigue property (2% attenuation after 1000 cycles), and remarkable sensitivity (52.4 kPa(-1)). |
源URL | [http://ir.nimte.ac.cn/handle/174433/21381] ![]() |
专题 | 2021专题_期刊论文 |
作者单位 | 1.Zhang, RY 2.Ying, WB 3.Zhu, J (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Biobased Polymer Mat Technol & Applicat Z, Ningbo 315201, Peoples R China. |
推荐引用方式 GB/T 7714 | Chen, Chao,Ying, Wu Bin,Li, Jiayi,et al. A Self-Healing and Ionic Liquid Affiliative Polyurethane toward a Piezo 2 Protein Inspired Ionic Skin[J]. ADVANCED FUNCTIONAL MATERIALS,2021. |
APA | Chen, Chao.,Ying, Wu Bin.,Li, Jiayi.,Kong, Zhengyang.,Li, Fenglong.,...&Zhu, Jin.(2021).A Self-Healing and Ionic Liquid Affiliative Polyurethane toward a Piezo 2 Protein Inspired Ionic Skin.ADVANCED FUNCTIONAL MATERIALS. |
MLA | Chen, Chao,et al."A Self-Healing and Ionic Liquid Affiliative Polyurethane toward a Piezo 2 Protein Inspired Ionic Skin".ADVANCED FUNCTIONAL MATERIALS (2021). |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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