A Creative Approach to Prepare a Macromolecular Flame Retardant with Flexibility: DOPO-Modified Epoxidized Polybutadiene
文献类型：期刊论文
| 作者 | Qin, Kangpei; Zhang, Xin; Xu, Yuan; Pang, Yongyan; Wang, Zhijun; Liu, Yinfeng; Zheng, Wenge |
| 刊名 | ACS APPLIED POLYMER MATERIALS
 |
| 出版日期 | 2021 |
| 卷号 | 3期号:10页码:4896-4903 |
| 关键词 | NATURAL-RUBBER EPOXY-RESINS POLYLACTIDE FLAMMABILITY TECHNOLOGY POLYMER |
| 英文摘要 | The incorporation of large loading of flame retardants generally causes embrittlement of materials. However, most of the rubbers and thermoplastic elastomers are flammable. Therefore, preparation of a flame retardant with potential toughening characteristics is urgently required for preparing materials with both good flame retardancy and toughness. The objective of the present work was to prepare a macromolecular flame retardant with good flexibility, that is, 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO)-modified epoxidized polybutadiene (EPB-DOPO) via a creative approach of two-step reactions. First, polybutadiene (PB) was partially epoxidized to generate EPB; second, the reactive flame retardant DOPO reacted with epoxy groups to generate EPB-DOPO. EPB-DOPO with three epoxidation degrees was prepared: EPB5%-DOPO, EPB10%-DOPO, and EPB15%-DOPO. The chemical structure of EPB-DOPO was confirmed with proton nuclear magnetic resonance (H-1 NMR) and Fourier transform infrared (FTIR) spectra. Thermogravimetric analysis (TGA) showed that EPB-DOPO had good thermal stability. EPB10%-DOPO and EPB15%-DOPO passed the UL-94 V-2 and V-0 rating, respectively, and the gas-phase flame retardation mechanism was deduced. The glass transition temperature (T-g) of EPB-DOPO prepared in this study was below -20 degrees C. Due to little char formation, EPB10%-DOPO and EPB15%-DOPO showed good resilience even after flame ignition. This study has provided a creative strategy to prepare a macromolecular flame retardant with good flexibility. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/21402]  |
| 专题 | 2021专题_期刊论文 |
| 作者单位 | Pang, YY (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Lab Polymers & Composites, Key Lab Biobased Polymer Mat Technol & Applicat Z, Ningbo 315201, Zhejiang, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Qin, Kangpei,Zhang, Xin,Xu, Yuan,et al. A Creative Approach to Prepare a Macromolecular Flame Retardant with Flexibility: DOPO-Modified Epoxidized Polybutadiene[J]. ACS APPLIED POLYMER MATERIALS,2021,3(10):4896-4903. |
| APA | Qin, Kangpei.,Zhang, Xin.,Xu, Yuan.,Pang, Yongyan.,Wang, Zhijun.,...&Zheng, Wenge.(2021).A Creative Approach to Prepare a Macromolecular Flame Retardant with Flexibility: DOPO-Modified Epoxidized Polybutadiene.ACS APPLIED POLYMER MATERIALS,3(10),4896-4903. |
| MLA | Qin, Kangpei,et al."A Creative Approach to Prepare a Macromolecular Flame Retardant with Flexibility: DOPO-Modified Epoxidized Polybutadiene".ACS APPLIED POLYMER MATERIALS 3.10(2021):4896-4903. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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