Stepwise Assembly of a Multicomponent Heterometallic Metal-Organic Framework via Th-6-Based Metalloligands
文献类型：期刊论文
| 作者 | Kong, Xianghe; Hu, Kongqiu; Huang, Zhiwei; Wu, Qunyan; Yu, Jipan; Mei, Lei; Chai, Zhifang; Nie, Changming; Shi, Weiqun |
| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2021 |
| 卷号 | 60期号:19页码:14535-14539 |
| 关键词 | COORDINATION |
| 英文摘要 | Herein we present a new metalloligand, Th6L12 [IHEP-10; L = 4-pyrazolecarboxylic acid (H2PyC)], which can be used to generate a novel multicomponent heterometallic metal-organic framework (MOF), [[Cu-3(mu(3)-OH)(NO3)(H2O)(2)](2)Th-6(mu O-3)(4)(mu(3)-OH)(4)(PyC)(6)(HPyC)(6)(H2O)(6)](NO3)(2) (IHEP-11), through further assembly with second [Cu3(mu 3-OH)(PyC)3] clusters. In IHEP-11, six Cu-3 clusters are connected by six NO3- anions to form an unprecedented annular Cu-18 cluster, which can be viewed as a 12-connected node to link with 12 Th-6 clusters, resulting a 4,12-connected shp net. Benefiting from the cationic framework and 3D porous structure, IHEP-11 can efficiently remove ReO4- (an analogue of radioactive (TcO4-)-Tc-99) from aqueous solution in a wide pH range. This work highlights the feasibility of constructing multicomponent MOFs through a step-by-step synthesis strategy based on metalloligands. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/21414]  |
| 专题 | 2021专题_期刊论文 |
| 作者单位 | 1.Hu, KQ 2.Shi, WQ (corresponding author), Chinese Acad Sci, Inst High Energy Phys, Lab Nucl Energy Chem, Beijing 100049, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Kong, Xianghe,Hu, Kongqiu,Huang, Zhiwei,et al. Stepwise Assembly of a Multicomponent Heterometallic Metal-Organic Framework via Th-6-Based Metalloligands[J]. INORGANIC CHEMISTRY,2021,60(19):14535-14539. |
| APA | Kong, Xianghe.,Hu, Kongqiu.,Huang, Zhiwei.,Wu, Qunyan.,Yu, Jipan.,...&Shi, Weiqun.(2021).Stepwise Assembly of a Multicomponent Heterometallic Metal-Organic Framework via Th-6-Based Metalloligands.INORGANIC CHEMISTRY,60(19),14535-14539. |
| MLA | Kong, Xianghe,et al."Stepwise Assembly of a Multicomponent Heterometallic Metal-Organic Framework via Th-6-Based Metalloligands".INORGANIC CHEMISTRY 60.19(2021):14535-14539. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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