Design of bio-based organic phase change materials containing a safety valve
文献类型：期刊论文
| 作者 | Wuliu, Yishun; Liu, Jingkai; Zhang, Liyue; Wang, Shuaipeng; Liu, Yuejun; Feng, Jianxiang; Liu, Xiaoqing |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2021 |
| 卷号 | 23期号:21页码:8643-8656 |
| 关键词 | THERMAL-ENERGY STORAGE CHANGE MATERIALS PCMS FATTY-ACIDS CARBON MATERIALS PERFORMANCE CONVERSION RESINS COMPOSITES RESISTANT |
| 英文摘要 | Energy efficiency and resource utilization are considered to be necessary for sustainable development. Organic phase change materials (PCMs) as an effective thermal energy storage tool have attracted great interest, but non-renewable ingredients, low stability and their unsafe nature largely restrict their sustainability. Herein, a series of bio-based benzoxazine-derived PCMs were developed, in which green preparation, efficient energy conversion, and safe utilization can be simultaneously achieved. Through the Mannich condensation reaction, novel PCMs can be easily synthesized with good yield and high atom economy by combining natural 3-pentadecylphenol (a cardanol derivative) and amine sources. The resulting PCMs exhibited adjustable latent heat (48.78-147.02 J g(-1)) by altering raw materials, which are close to their commercial unsustainable counterparts. As an example, C-aa-12 also showed considerable recycling ability after 100 times repeated use. In addition, due to the designed structure, as-prepared PCMs also possessed more excellent properties of thermal stability (T-d50% was increased by 65.1%) and flame retardancy (HRR was reduced by 39.4%) compared with traditional ones, making them promising in a wider application field. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/21424]  |
| 专题 | 2021专题_期刊论文 |
| 作者单位 | 1.Liu, XQ (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Zhejiang, Peoples R China. 2.Feng, JX (corresponding author), Hunan Univ Technol, Coll Packaging & Mat Engn, Zhuzhou 412007, Peoples R China. 3.Liu, XQ (corresponding author), Univ Chinese Acad Sci, Beijing 100049, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Wuliu, Yishun,Liu, Jingkai,Zhang, Liyue,et al. Design of bio-based organic phase change materials containing a safety valve[J]. GREEN CHEMISTRY,2021,23(21):8643-8656. |
| APA | Wuliu, Yishun.,Liu, Jingkai.,Zhang, Liyue.,Wang, Shuaipeng.,Liu, Yuejun.,...&Liu, Xiaoqing.(2021).Design of bio-based organic phase change materials containing a safety valve.GREEN CHEMISTRY,23(21),8643-8656. |
| MLA | Wuliu, Yishun,et al."Design of bio-based organic phase change materials containing a safety valve".GREEN CHEMISTRY 23.21(2021):8643-8656. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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