Heterogeneous Fluorescent Organohydrogel Enables Dynamic Anti-Counterfeiting
文献类型:期刊论文
作者 | Le, Xiaoxia; Shang, Hui; Wu, Shuangshuang; Zhang, Jiawei; Liu, Mingjie; Zheng, Yinfei; Chen, Tao |
刊名 | ADVANCED FUNCTIONAL MATERIALS
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出版日期 | 2021 |
英文摘要 | Fluorescent patterns showing the unique color change in response to external stimuli are of considerable interest for their applications in anti-counterfeiting. However, there is still a lack of intelligent fluorescent patterns with high-security levels, presenting a dynamic display of encrypted information. In this study, a fluorescent organohydrogel is fabricated through a two-step interpenetrating technique, leading to the co-existence of naphthalimide moieties (DEAN, green-yellow fluorescent monomer) contained Poly(N,N-dimethylacrylamide) (PDMA) hydrogel network and Polyoctadecyl methacrylate (PSMA) organogel network bearing spiropyran moieties (SPMA, photochromic monomer). Due to the unique heterogeneous networks, the fluorescence color goes through a continuous change from green to yellow to red via the fluorescence resonance energy transfer (FRET) process with the extension of irradiation time. In addition, when H+ is introduced into the system, SP units exhibit transformation into the protonated merocyanine (MCH+) rather than merocyanine (MC) under UV light, which inhibits the FRET process. By selectively being treated with H+, the fluorescent organohydrogel can act as an effective platform for encrypting secret information, making them more difficult to forge. |
源URL | [http://ir.nimte.ac.cn/handle/174433/21472] ![]() |
专题 | 2021专题_期刊论文 |
作者单位 | 1.Chen, T (corresponding author), Chinese Acad Sci, Key Lab Marine Mat & Related Technol, Zhejiang Key Lab Marine Mat & Protect Technol, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China. 2.Liu, MJ (corresponding author), Beihang Univ, Key Lab Bioinspired Smart Interfacial Sci & Techn, Minist Educ, Sch Chem, Beijing 100191, Peoples R China. |
推荐引用方式 GB/T 7714 | Le, Xiaoxia,Shang, Hui,Wu, Shuangshuang,et al. Heterogeneous Fluorescent Organohydrogel Enables Dynamic Anti-Counterfeiting[J]. ADVANCED FUNCTIONAL MATERIALS,2021. |
APA | Le, Xiaoxia.,Shang, Hui.,Wu, Shuangshuang.,Zhang, Jiawei.,Liu, Mingjie.,...&Chen, Tao.(2021).Heterogeneous Fluorescent Organohydrogel Enables Dynamic Anti-Counterfeiting.ADVANCED FUNCTIONAL MATERIALS. |
MLA | Le, Xiaoxia,et al."Heterogeneous Fluorescent Organohydrogel Enables Dynamic Anti-Counterfeiting".ADVANCED FUNCTIONAL MATERIALS (2021). |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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