Toughening and strengthening epoxy resin with flame retardant molecular structure based on tyrosine
文献类型:期刊论文
作者 | Sun, Jinhao; Qian, Lijun; Li, Juan |
刊名 | POLYMER
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出版日期 | 2021 |
卷号 | 230 |
关键词 | MECHANICAL-PROPERTIES TEMPERATURE AGENT COMPOUND POLYMERS ETHER |
英文摘要 | It is difficult to strengthen and toughen epoxy resin (EP) and concurrently obtain good flame retardancy. A novel flame retardant marked as TFD was prepared by tyrosine (Tyr), furfuraldehyde (FA) and 9,10-Dihydro-9-oxa-10phosphaphenanthrene 10-oxide (DOPO) and co-cured with EP. Only 6 wt% TFD makes EP achieve UL-94 V0 and limited oxygen index (LOI) value 32.4 vol% revealing the high flame retardant efficiency. Furthermore, the tensile and impact strength of EP-8TFD are 29.3 % and 84.4 % higher than that of EP indicating strengthening and toughening effect of TFD. TFD can chemically bond into EP networks via its carboxyl and phenolic hydroxyl reacting with EP leading to good tensile properties. The high rigidity of DOPO forms holes between molecular chains, which eliminates stress concentration and improves impact strength. The strength, toughness and flame retardancy of EP are regulated by simple molecular structure, which provides a good idea for integration of structure and performance. |
源URL | [http://ir.nimte.ac.cn/handle/174433/21485] ![]() |
专题 | 2021专题_期刊论文 |
作者单位 | Li, J (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo Key Lab Polymer Mat, Ningbo 315201, Zhejiang, Peoples R China. |
推荐引用方式 GB/T 7714 | Sun, Jinhao,Qian, Lijun,Li, Juan. Toughening and strengthening epoxy resin with flame retardant molecular structure based on tyrosine[J]. POLYMER,2021,230. |
APA | Sun, Jinhao,Qian, Lijun,&Li, Juan.(2021).Toughening and strengthening epoxy resin with flame retardant molecular structure based on tyrosine.POLYMER,230. |
MLA | Sun, Jinhao,et al."Toughening and strengthening epoxy resin with flame retardant molecular structure based on tyrosine".POLYMER 230(2021). |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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