Small-molecular donor guest achieves rigid 18.5% and flexible 15.9% efficiency organic photovoltaic via fine-tuning microstructure morphology
文献类型:期刊论文
作者 | Chen, Zhenyu; Song, Wei; Yu, Kuibao; Ge, Jinfeng; Zhang, Jinsheng; Xie, Lin; Peng, Ruixiang; Ge, Ziyi |
刊名 | JOULE
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出版日期 | 2021 |
卷号 | 5期号:9页码:2395-2407 |
关键词 | SOLAR-CELLS ACCEPTOR PACKING |
英文摘要 | Incorporation of crystalline small molecule into host binary systems to finely tune film morphology is demonstrated to be an effective method to improve photovoltaic performance for organic solar cells (OSCs). In this work, two small molecular donors with similar chemical structures, G17 and G19, were designed and synthesized. Interestingly, the G17-containing sp(3-)carbon p-bridge features an amorphous orientation, whereas the silicon-substituted G19 exhibits an extremely ordered edge- on orientation. When doped into D18-Cl:Y6 host system, the G19-based ternary device exhibits a largely improved power conversion efficiency (PCE) of 18.53%, which is among the highest PCEs for OSCs. By contrast, the G17-based ternary device only delivers a relatively low PCE of 17.13%. Correspondingly, flexible OSCs based on the G19 ternary active layer also give an excellent PCE of 15.9%. These results highlight that incorporating highly ordered molecular donor can be an effective method to construct highly efficient OSCs. |
源URL | [http://ir.nimte.ac.cn/handle/174433/21488] ![]() |
专题 | 2021专题_期刊论文 |
作者单位 | 1.Ge, ZY (corresponding author), Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China. 2.Ge, ZY (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China. |
推荐引用方式 GB/T 7714 | Chen, Zhenyu,Song, Wei,Yu, Kuibao,et al. Small-molecular donor guest achieves rigid 18.5% and flexible 15.9% efficiency organic photovoltaic via fine-tuning microstructure morphology[J]. JOULE,2021,5(9):2395-2407. |
APA | Chen, Zhenyu.,Song, Wei.,Yu, Kuibao.,Ge, Jinfeng.,Zhang, Jinsheng.,...&Ge, Ziyi.(2021).Small-molecular donor guest achieves rigid 18.5% and flexible 15.9% efficiency organic photovoltaic via fine-tuning microstructure morphology.JOULE,5(9),2395-2407. |
MLA | Chen, Zhenyu,et al."Small-molecular donor guest achieves rigid 18.5% and flexible 15.9% efficiency organic photovoltaic via fine-tuning microstructure morphology".JOULE 5.9(2021):2395-2407. |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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