An anti-stress relaxation, anti-fatigue, mildew proof and self-healing poly (thiourethane-urethane) for durably stretchable electronics
文献类型：期刊论文
| 作者 | Ying, Wu Bin; Liu, Haixiong; Gao, Peiyuan; Kong, Zhengyang; Hu, Han; Wang, Kai; Shen, Ang; Jin, Zhijin; Zheng, Lin; Guo, Hongxia |
| 刊名 | CHEMICAL ENGINEERING JOURNAL
 |
| 出版日期 | 2021 |
| 卷号 | 420 |
| 关键词 | MOLECULE FORCE SPECTROSCOPY D-GLUCOSE POLYURETHANE ELASTICITY ELASTOMERS RECOVERY CRYSTAL SKIN |
| 英文摘要 | Considering the complicated environment in daily use of stretchable devices, the capabilities of anti-stress relaxation, anti-fatigue, anti-fungal and self-healing are very much appreciated, and the above four functionalities largely depend on the elastic matrix. Here, these demands are fulfilled by a poly(thiourethane-urethane) elastomer CBPU-3. In detail, a large amount of cyclohexane rings, with completely reversible boat-chair conformational transition, are introduced into the backbone of poly(thiourethane-urethane), and such nonplanar ring imparts molecular elasticity and modulus into the elastomer, resulting in remarkable anti-stress relaxation and anti-fatigue abilities. Even after 20 h fixation at 300% strain and 1000 times cyclic tensile (50% strain), the recovery ratio could still be higher than 98%, and its stable microstructure is proved by SAXS scattering patterns. In addition, the thioether bond ensures the effective mildew proof ability, and the mechanical properties and transmittance change little even after a severe mildew pollution for 30 days. Simultaneously, the relatively lower bond energy of C-S (62.0 Kcal/mol) in thiourethane bonds endowes the poly(thiourethane-urethane) with self-healing capability (highest: 40 mu m/min at 80 degrees C). Finally, the durability and usability of the deformable resistive sensor array based on this elastomer as the matrix are drastically enhanced due to the above integrated functionalities. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/21500]  |
| 专题 | 2021专题_期刊论文 |
| 作者单位 | Zhang, RY (corresponding author), Chinese Acad Sci, Key Lab Biobased Polymer Mat Technol & Applicat Z, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Ying, Wu Bin,Liu, Haixiong,Gao, Peiyuan,et al. An anti-stress relaxation, anti-fatigue, mildew proof and self-healing poly (thiourethane-urethane) for durably stretchable electronics[J]. CHEMICAL ENGINEERING JOURNAL,2021,420. |
| APA | Ying, Wu Bin.,Liu, Haixiong.,Gao, Peiyuan.,Kong, Zhengyang.,Hu, Han.,...&Zhu, Jin.(2021).An anti-stress relaxation, anti-fatigue, mildew proof and self-healing poly (thiourethane-urethane) for durably stretchable electronics.CHEMICAL ENGINEERING JOURNAL,420. |
| MLA | Ying, Wu Bin,et al."An anti-stress relaxation, anti-fatigue, mildew proof and self-healing poly (thiourethane-urethane) for durably stretchable electronics".CHEMICAL ENGINEERING JOURNAL 420(2021). |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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