GO-Ti3C2 two-dimensional heterojunction nanomaterial for anticorrosion enhancement of epoxy zinc-rich coatings
文献类型:期刊论文
作者 | Shen, Lu; Zhao, Wenjie; Wang, Kui; Xu, Jianguang |
刊名 | JOURNAL OF HAZARDOUS MATERIALS |
出版日期 | 2021 |
卷号 | 417 |
关键词 | TI3C2 MXENE NANOSHEETS CORROSION PROTECTION GRAPHENE OXIDE POWDER COATINGS PERFORMANCE NANOCOMPOSITE CONCRETE COMPOSITES GRAPHITE BEHAVIOR |
英文摘要 | MXenes are a unique family of two-dimensional (2D) transition metal carbides and/or nitrides, which have been proven useful for energy storage, water purification, and biomedical applications. Herein, a kind of heterojunction structure was designed by grafting highly conductive MXene (Ti3C2) on the graphene oxide (GO) nanosheets, which was confirmed by Fourier transform infrared (FT-IR) spectroscopy, X-ray photoelectronic spectroscopy (XPS) and Raman results. Open circuit potential (OCP), electrochemical impedance spectroscopy (EIS) and salt spray measurements corroborated that inclusion of 0.5 wt% Ti3C2 or GO-Ti3C2 into epoxy zinc-rich coating (ZRC) effectively enhance the cathodic protection capability. Additionally, superior corrosion resistance was achieved by incorporation of GO-Ti3C2 into ZRC since GO-Ti3C2 in the coating improved the utilization rate of zinc particles and GO provided barrier protection for inhibiting the diffusion of corrosive agents. At the end of immersion, Rc value of ZRC/GO-Ti3C2 coating was 3.047 & times; 104 omega & sdot;cm2, which was one order of magnitude higher than that of ZRC coating. Scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS) measurements demonstrated that ZRC/GO-Ti3C2 coating exhibited lower speed of zinc particles oxidation and intact steel substrate. Hence, ZRC/GO-Ti3C2 coating exhibited the optimal corrosion resistance among the four kinds of coatings. |
源URL | [http://ir.nimte.ac.cn/handle/174433/21514] |
专题 | 2021专题_期刊论文 |
作者单位 | Zhao, WJ (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Marine Mat & Related Technol, Ningbo 315201, Peoples R China. |
推荐引用方式 GB/T 7714 | Shen, Lu,Zhao, Wenjie,Wang, Kui,et al. GO-Ti3C2 two-dimensional heterojunction nanomaterial for anticorrosion enhancement of epoxy zinc-rich coatings[J]. JOURNAL OF HAZARDOUS MATERIALS,2021,417. |
APA | Shen, Lu,Zhao, Wenjie,Wang, Kui,&Xu, Jianguang.(2021).GO-Ti3C2 two-dimensional heterojunction nanomaterial for anticorrosion enhancement of epoxy zinc-rich coatings.JOURNAL OF HAZARDOUS MATERIALS,417. |
MLA | Shen, Lu,et al."GO-Ti3C2 two-dimensional heterojunction nanomaterial for anticorrosion enhancement of epoxy zinc-rich coatings".JOURNAL OF HAZARDOUS MATERIALS 417(2021). |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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