Hidden Charge Order in an Iron Oxide Square-Lattice Compound
文献类型:期刊论文
作者 | Kim, Jung-Hwa; Peets, Darren C.; Reehuis, Manfred; Adler, Peter; Maljuk, Andrey; Ritschel, Tobias; Allison, Morgan C.; Geck, Jochen; Mardegan, Jose R. L.; Perez, Pablo J. Bereciartua |
刊名 | PHYSICAL REVIEW LETTERS
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出版日期 | 2021 |
卷号 | 127期号:9 |
关键词 | NEUTRON-DIFFRACTION ELECTRONIC-STATE DISPROPORTIONATION TRANSITION SR3FE2O7 |
英文摘要 | Since the discovery of charge disproportionation in the FeO2 square-lattice compound Sr3Fe2O7 by Mossbauer spectroscopy more than fifty years ago, the spatial ordering pattern of the disproportionated charges has remained hidden to conventional diffraction probes, despite numerous x-ray and neutron scattering studies. We have used neutron Larmor diffraction and Fe K-edge resonant x-ray scattering to demonstrate checkerboard charge order in the FeO2 planes that vanishes at a sharp second-order phase transition upon heating above 332 K. Stacking disorder of the checkerboard pattern due to frustrated interlayer interactions broadens the corresponding superstructure reflections and greatly reduces their amplitude, thus explaining the difficulty of detecting them by conventional probes. We discuss the implications of these findings for research on hidden order in other materials. |
源URL | [http://ir.nimte.ac.cn/handle/174433/21545] ![]() |
专题 | 2021专题_期刊论文 |
作者单位 | Keimer, B (corresponding author), Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany. |
推荐引用方式 GB/T 7714 | Kim, Jung-Hwa,Peets, Darren C.,Reehuis, Manfred,et al. Hidden Charge Order in an Iron Oxide Square-Lattice Compound[J]. PHYSICAL REVIEW LETTERS,2021,127(9). |
APA | Kim, Jung-Hwa.,Peets, Darren C..,Reehuis, Manfred.,Adler, Peter.,Maljuk, Andrey.,...&Keimer, Bernhard.(2021).Hidden Charge Order in an Iron Oxide Square-Lattice Compound.PHYSICAL REVIEW LETTERS,127(9). |
MLA | Kim, Jung-Hwa,et al."Hidden Charge Order in an Iron Oxide Square-Lattice Compound".PHYSICAL REVIEW LETTERS 127.9(2021). |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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