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A quasi-intercalation reaction for fast sulfur redox kinetics in solid-state lithium-sulfur batteries

文献类型：期刊论文

作者Li, Chuang5; Zhang, Qi5; Sheng, Jinzhi5; Chen, Biao4,5; Gao, Runhua5; Piao, Zhihong5; Zhong, Xiongwei5; Han, Zhiyuan5; Zhu, Yanfei5; Wang, Jiulin3
刊名ENERGY & ENVIRONMENTAL SCIENCE
出版日期2022-08-22
页码12
ISSN号1754-5692
DOI10.1039/d2ee01820a
通讯作者Zhou, Guangmin(guangminzhou@sz.tsinghua.edu.cn) ; Cheng, Hui-Ming()
英文摘要Solid-state lithium-sulfur (Li-S) batteries have been recognized as a competitive candidate for next-generation energy storage systems due to their high energy density and safety. However, the slow redox kinetics between S and Li2S and the large volume change of sulfur during charge/discharge have hindered the development of solid-state Li-S batteries. We report a solid-state Li-S battery using a polymer-in-salt solid-state electrolyte, in which the sulfur is anchored in a polyacrylonitrile (PAN) substrate during cycling, avoiding the formation of Li2S and thus resulting in much faster redox kinetics and a smaller volume change than the conventional solid-state Li-S batteries. The quasi-intercalation reaction in the system is achieved with the assistance of the residual N,N-dimethylformamide (DMF), which helps strengthen the C-S bond. As a result, the solid-state Li-sulfurized PAN (SPAN) batteries have a superb rate capability at room temperature, even higher than those of liquid-state Li-S batteries, due to the faster redox kinetics and smaller volume change without solid-solid S to Li2S conversion which is present in liquid-state Li-SPAN batteries. This is the first report of the redox kinetics of solid-state Li-SPAN batteries being increased by changing the bond-strength of the C-S bond instead of using catalysts. This technique opens up new opportunities for designing high-performance solid-state Li-S batteries.
资助项目National Key Research and Development Program of China[2021YFB2500200] ; National Key Research and Development Program of China[2019YFA0705700] ; National Natural Science Foundation of China[52072205] ; National Natural Science Foundation of China[U21A20174] ; Overseas Research Cooperation Fund of Tsinghua Shenzhen International Graduate School ; Postdoctoral Science Foundation of China[2022M711752] ; Shenzhen Geim Graphene Center
WOS研究方向Chemistry ; Energy & Fuels ; Engineering ; Environmental Sciences & Ecology
语种英语
出版者ROYAL SOC CHEMISTRY
WOS记录号WOS:000850628800001
资助机构National Key Research and Development Program of China ; National Natural Science Foundation of China ; Overseas Research Cooperation Fund of Tsinghua Shenzhen International Graduate School ; Postdoctoral Science Foundation of China ; Shenzhen Geim Graphene Center
源URL[http://ir.imr.ac.cn/handle/321006/175031]  
专题金属研究所_中国科学院金属研究所
通讯作者Zhou, Guangmin; Cheng, Hui-Ming
作者单位1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
2.Chinese Acad Sci, Fac Mat Sci & Engn, Inst Technol Carbon Neutral, Shenzhen Inst Adv Technol, Shenzhen 518055, Peoples R China
3.Xinjiang Univ, Coll Chem, Urumqi 8300417, Xinjiang, Peoples R China
4.Tianjin Univ, Sch Mat Sci & Engn, Tianjin Key Lab Composite & Funct Mat, Tianjin 300350, Peoples R China
5.Tsinghua Univ, Shenzhen Geim Graphene Ctr, Tsinghua Shenzhen Int Grad Sch, Shenzhen 518055, Peoples R China
推荐引用方式
GB/T 7714		 Li, Chuang,Zhang, Qi,Sheng, Jinzhi,et al. A quasi-intercalation reaction for fast sulfur redox kinetics in solid-state lithium-sulfur batteries[J]. ENERGY & ENVIRONMENTAL SCIENCE,2022:12.
APA Li, Chuang.,Zhang, Qi.,Sheng, Jinzhi.,Chen, Biao.,Gao, Runhua.,...&Cheng, Hui-Ming.(2022).A quasi-intercalation reaction for fast sulfur redox kinetics in solid-state lithium-sulfur batteries.ENERGY & ENVIRONMENTAL SCIENCE,12.
MLA Li, Chuang,et al."A quasi-intercalation reaction for fast sulfur redox kinetics in solid-state lithium-sulfur batteries".ENERGY & ENVIRONMENTAL SCIENCE (2022):12.

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来源：金属研究所

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