Sm cluster on hexagonal boron nitride supported by Ir(111): Formation of magnetic cluster superlattice Sm-13@h-BN|Ir(111)
文献类型：期刊论文
| 作者 | Chen, Qiang3; Chen, Yaqing3; Ju, Meng3; Shi, Xuan1,2 ; Wang, Peng3; Chen, Hong3; Yuan, Hongkuan3
|
| 刊名 | APPLIED SURFACE SCIENCE
 |
| 出版日期 | 2022-12-01 |
| 卷号 | 604页码:10 |
| ISSN号 | 0169-4332 |
| 关键词 | Rare earth cluster Cluster superlattice |
| DOI | 10.1016/j.apsusc.2022.154478 |
| 通讯作者 | Shi, Xuan(shixuan@cigit.ac.cn) ; Yuan, Hongkuan(yhk10@swu.edu.cn) |
| 英文摘要 | The goal toward the ultimate density limit of magnetic information storage is now focused on the creations of identical magnetic clusters as well as their arrangements on a template surface for obtaining an equidistant, monodisperse and equally oriented pattern. To achieve this goal, the combination of rare-earth (RE) cluster and specific template is a viable route, e.g., h-BN monolayer on Ir(111) surface within a corrugated moire structure (h-BN|Ir(111)) can act as a promising template to steer the intrinsically magnetic RE cluster in a well-defined orientation. Combining ab inito molecular dynamic (AIMD) simulation and spin-orbital coupling density function theory (DFT) calculations, we report that magnetic Sm-13 cluster can be stably deposited at the pore region of h-BN|Ir(111) template. The low-lying moire region potential of h-BN|Ir(111) template, stable icosahedron structure of Sm-13 cluster, and strong hybridization of Sm-5d6s orbitals with B/N-sp orbitals, play the synergetically roles to form Sm-13@h-BN|Ir(111) cluster superlattice. The local magnetic moments of Sm atoms in Sm-13 cluster are found to be robust against the structural configuration, localized site and inter-atom magnetic coupling, because their highly localized 4f states hybridize less with the spd states. Nevertheless, different deposition orientations and consequently the altered bonding interactions between Sm atoms and h-BN monolayer lead to different magnetic orders among Sm atoms. The appearances of large magnetic moment and giant magnetic anisotropy energy (MAE) of Sm-13 cluster as well as its high deposition stability render Sm-13@h-BN|Ir(111) for potential application of magnetic storage. |
| 资助项目 | National Natural Science Founda-tion of China[11874306] ; National Natural Science Founda-tion of China[12174320] ; Natural Science Foun-dation of Chongqing, China[cstc2021jcyj-msxmX0209] ; Natural Science Foun-dation of Chongqing, China[cstc2022ycjh-bgzxm0127] |
| WOS研究方向 | Chemistry ; Materials Science ; Physics |
| 语种 | 英语 |
| 出版者 | ELSEVIER |
| WOS记录号 | WOS:000848332300001 |
| 源URL | [http://119.78.100.138/handle/2HOD01W0/16515]  |
| 专题 | 中国科学院重庆绿色智能技术研究院 |
| 通讯作者 | Shi, Xuan; Yuan, Hongkuan |
| 作者单位 | 1.Univ Chinese Acad Sci, Coll Artificial Intelligence, Chongqing Sch, Chongqing 400714, Peoples R China 2.Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Ctr Quantum Informat Technol, Chongqing 400714, Peoples R China 3.Southwest Univ, Sch Phys Sci & Technol, Chongqing 400715, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Qiang,Chen, Yaqing,Ju, Meng,et al. Sm cluster on hexagonal boron nitride supported by Ir(111): Formation of magnetic cluster superlattice Sm-13@h-BN|Ir(111)[J]. APPLIED SURFACE SCIENCE,2022,604:10. |
| APA | Chen, Qiang.,Chen, Yaqing.,Ju, Meng.,Shi, Xuan.,Wang, Peng.,...&Yuan, Hongkuan.(2022).Sm cluster on hexagonal boron nitride supported by Ir(111): Formation of magnetic cluster superlattice Sm-13@h-BN|Ir(111).APPLIED SURFACE SCIENCE,604,10. |
| MLA | Chen, Qiang,et al."Sm cluster on hexagonal boron nitride supported by Ir(111): Formation of magnetic cluster superlattice Sm-13@h-BN|Ir(111)".APPLIED SURFACE SCIENCE 604(2022):10. |
入库方式： OAI收割
来源：重庆绿色智能技术研究院
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