Electrodeposition of a dendrite-free 3D Al anode for improving cycling of an aluminum-graphite battery
文献类型：期刊论文
| 作者 | Li, Junfeng; Hui, Kwan San8; Ji, Shunping; Zha, Chenyang; Yuan, Chengzong; Wu, Shuxing7; Bin F(宾峰) ; Fan, Xi5; Chen, Fuming4; Shao, Zongping2,3
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| 刊名 | CARBON ENERGY
 ; 2
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| 出版日期 | 2022-03 |
| 卷号 | 4页码:155 |
| 关键词 | 3D Al anode ionic liquid metallic plating/stripping stability |
| DOI | 10.1002/cey2.155 |
| 英文摘要 | Aluminum-metal batteries show great potential as next-generation energy storage due to their abundant resources and intrinsic safety. However, the crucial limitations of metallic Al anodes, such as dendrite and corrosion problems in conventional aluminum-metal batteries, remain challenging and elusive. Here, we report a 11el electrodeposition strategy to prepare an optimized 3D Al anode on carbon cloth with an uniform deposition morphology, low local current density, and mitigatory volume change. The symmetrical cells with the 3D Al anode show superior stable cycling (>450 h) and low-voltage hysteresis (similar to 170 mV) at 0.5 mA cm(-2). High reversibility (similar to 99.7%) is achieved for the Al plating/stripping. The graphite vertical bar vertical bar Al-4/CC full batteries show a long lifespan of 800 cycles with 54 mAh g(-1) capacity at a high current density of 1000 mA g(-1), benefiting from the high capacitive-controlled distribution. This study proposes a 11el strategy to design 3D Al anodes for metallic-Al-based batteries by eliminating the problems of planar Al anodes and realizing the potential applications of aluminum-graphite batteries. |
| 学科主题 | Chemistry, Physical ; Energy & Fuels ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| 分类号 | 一类 |
| 语种 | 英语 |
| WOS记录号 | WOS:000713345500001 |
| 资助机构 | Science and Technology Development Fund, Macau SAR [0191/2017/A3, 0041/2019/A1, 0046/2019/AFJ, 0021/2019/AIR] ; University of Macau [MYRG2017-00216-FST, MYRG2018-00192-IAPME] ; UEA funding, Science and Technology Program of Guangzhou [2019050001] ; National Key Research and Development Program of China [2019YFE0198000] ; Pearl River Talent Program [2019QN01L951] |
| 其他责任者 | Hui, KN (corresponding author), Univ Macau, Joint Key Lab, Inst Appl Phys & Mat Engn, Minist Educ, Ave Univ, Taipa 999078, Macao, Peoples R China. ; Hui, KS (corresponding author), Univ East Anglia, Sch Engn, Fac Sci, Norwich NR4 7TJ, Norfolk, England. ; Shao, ZP (corresponding author), Nanjing Tech Univ, Coll Chem Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 211816, Peoples R China. |
| 源URL | [http://dspace.imech.ac.cn/handle/311007/90150]  |
| 专题 | 力学研究所_高温气体动力学国家重点实验室 |
| 作者单位 | 1.Curtin Univ, WA Sch Mines Minerals Energy & Chem Engn WASM MEC, Perth, WA, Australia 2.Nanjing Tech Univ, Coll Chem Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 211816, Peoples R China 3.South China Normal Univ, Sch Phys & Telecommun Engn, Guangdong Prov Key Lab Quantum Engn & Quantum Mat, Guangzhou, Peoples R China 4.Chinese Acad Sci, Ningbo Inst Mat Technol, Engn, Ningbo, Peoples R China 5.Chinese Acad Sci, Inst Mech, State Key Lab High Temp Gas Dynam, Beijing, Peoples R China 6.Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou, Peoples R China 7.Univ East Anglia, Sch Engn, Fac Sci, Norwich NR4 7TJ, Norfolk, England 8.Univ Macau, Joint Key Lab, Inst Appl Phys & Mat Engn, Minist Educ, Ave Univ, Taipa 999078, Macao, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Junfeng,Hui, Kwan San,Ji, Shunping,et al. Electrodeposition of a dendrite-free 3D Al anode for improving cycling of an aluminum-graphite battery[J]. CARBON ENERGY, 2,2022,4:155. |
| APA | Li, Junfeng.,Hui, Kwan San.,Ji, Shunping.,Zha, Chenyang.,Yuan, Chengzong.,...&Bin F.(2022).Electrodeposition of a dendrite-free 3D Al anode for improving cycling of an aluminum-graphite battery.CARBON ENERGY,4,155. |
| MLA | Li, Junfeng,et al."Electrodeposition of a dendrite-free 3D Al anode for improving cycling of an aluminum-graphite battery".CARBON ENERGY 4(2022):155. |
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