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Solid-contact polymeric membrane ion-selective electrodes based on electrodeposited NiCo2S4 nanosheet arrays br

文献类型：期刊论文

作者Li, Yanhong1,4; Li, Jinghui4; Qin, Wei2,3,4
刊名TALANTA
出版日期2023
卷号251页码:7
ISSN号0039-9140
关键词Ion -selective electrodes Nickel cobalt sulfide Solid contact Quasi-superhydrophobic Electrodeposition
DOI10.1016/j.talanta.2022.123797
通讯作者Li, Jinghui(jinghuili@yic.ac.cn)
英文摘要In situ growth of quasi-superhydrophobic porous NiCo2S4 nanosheet arrays with a one-step electrodeposition method was provided. A calcium ion-selective electrodes (Ca2+-ISE) was subsequently constructed by using the prepared NiCo2S4 as a solid contact layer. The proposed Ca2+-ISE exhibits a good Nernstian slope of 30.7 +/- 0.3 mV/dec and a detection limit of 1.6 x 10-7 M. Due to the large redox capacitance of 1.8 mF, the Ca2+-ISE based on NiCo2S4 nanosheet arrays shows a high potential stability of 1.9 +/- 0.5 mu V/h over 90 h. Excellent reproducibilities for the NiCo2S4-based Ca2+-ISEs can be obtained with the single batch and batch-to-batch E degrees standard deviations of 0.3 (n = 6) and 0.7 mV (n = 5), respectively. The NiCo2S4 nanosheet arrays have a large contact angle of 148 +/- 1.4 degrees, which effectively suppresses the formation of a water layer at the sensing membrane/NiCo2S4 interface.
WOS关键词GRAPHENE ; CARBON ; SENSOR ; FILM ; POLYANILINE ; COMPOSITE ; SURFACE
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000848101100003
资助机构National Natural Science Foundation of China ; Key Deployment Project of Centre for Ocean Mega -Research of Science , Chinese Acad- emy of Sciences ; Natural Science Foundation of Shandong Province ; National Key Research and Development Program of China ; Taishan Scholar Program of Shandong Province
源URL[http://ir.yic.ac.cn/handle/133337/31658]  
专题烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室
烟台海岸带研究所_近岸生态与环境实验室
通讯作者Li, Jinghui
作者单位1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
2.Chinese Acad Sci, Ctr Ocean Mega Sci, Qingdao 266071, Shandong, Peoples R China
3.Pilot Natl Lab Marine Sci & Technol Qingdao, Lab Marine Biol & Biotechnol, Shandong 266237, Peoples R China
4.Chinese Acad Sci, Yantai Inst Coastal Zone Res YIC, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Shandong Key Lab Coastal Environm Proc, Yantai 264003, Shandong, Peoples R China
推荐引用方式
GB/T 7714		 Li, Yanhong,Li, Jinghui,Qin, Wei. Solid-contact polymeric membrane ion-selective electrodes based on electrodeposited NiCo2S4 nanosheet arrays br[J]. TALANTA,2023,251:7.
APA Li, Yanhong,Li, Jinghui,&Qin, Wei.(2023).Solid-contact polymeric membrane ion-selective electrodes based on electrodeposited NiCo2S4 nanosheet arrays br.TALANTA,251,7.
MLA Li, Yanhong,et al."Solid-contact polymeric membrane ion-selective electrodes based on electrodeposited NiCo2S4 nanosheet arrays br".TALANTA 251(2023):7.

入库方式： OAI收割

来源：烟台海岸带研究所

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