Determination of Major, Minor Elements in the Samples of SrCO3 Productby X-Ray Fluorescence Spectrometry
文献类型：期刊论文
| 作者 | Dong Ya-ping ; Feng Hai-tao; Liu Xin; Meng Qing-fen; Bian Shao-ju
|
| 刊名 | SPECTROSCOPY AND SPECTRAL ANALYSIS
 |
| 出版日期 | 2009 |
| 卷号 | 29期号:8页码:2268-2271 |
| 关键词 | X-ray fluorescence spectrometry Pressed power sample Strontium |
| ISSN号 | 1000-0593 |
| 语种 | In the present paper a method for the determination of strontium, barium, calcium, magnesium, silicon, iron, aluminum and sulfur in the product of strontium carbonate by X-ray fluorescence spectrometry with pressed powder sample preparation was developed, and the standard samples were synthesized by high purity reagent. As the contents of strontium in the product of strontium carbonate were very high, the phenomenon of spectrum-peak-saturated occurred and the count rate was overflowed according to the measuring condition which was automatically given by the software system of X-ray fluorescence spectrometry. As a result, the deviation of the measurement is greater. According to analyzing the measuring condition of strontium, a method was given for reducing the count rate by reducing the measuring power of strontium, thus' achieving the goal of measurement. When sulfate was measured with pressed powder sample, the results were enhanced with the increase in measuring number. In light of this situation, a method was proposed to solve the problem. As the self-forming characteristic of the product of strontium carbonate was not so well, it was very difficult to press the sample successfully. So, the condition of squash method involving the kinds of the adhesives, the mixing technique with powder sample and the pressing-time technique was discussed. During making the sample, it was found that the effects of pellet formation were better if the time could be delayed by 120 seconds. Matrix effect was corrected by alpha coefficient method, the accuracy of the method was evaluated by analysis of synthetic sample. Detection limits of 0.623-107.6 mg.g(-1) were obtained. The results were in good agreement with certified values with precision of < 2.5% RSD. In the present paper a method for the determination of strontium, barium, calcium, magnesium, silicon, iron, aluminum and sulfur in the product of strontium carbonate by X-ray fluorescence spectrometry with pressed powder sample preparation was developed, and the standard samples were synthesized by high purity reagent. As the contents of strontium in the product of strontium carbonate were very high, the phenomenon of spectrum-peak-saturated occurred and the count rate was overflowed according to the measuring condition which was automatically given by the software system of X-ray fluorescence spectrometry. As a result, the deviation of the measurement is greater. According to analyzing the measuring condition of strontium, a method was given for reducing the count rate by reducing the measuring power of strontium, thus' achieving the goal of measurement. When sulfate was measured with pressed powder sample, the results were enhanced with the increase in measuring number. In light of this situation, a method was proposed to solve the problem. As the self-forming characteristic of the product of strontium carbonate was not so well, it was very difficult to press the sample successfully. So, the condition of squash method involving the kinds of the adhesives, the mixing technique with powder sample and the pressing-time technique was discussed. During making the sample, it was found that the effects of pellet formation were better if the time could be delayed by 120 seconds. Matrix effect was corrected by alpha coefficient method, the accuracy of the method was evaluated by analysis of synthetic sample. Detection limits of 0.623-107.6 mg.g(-1) were obtained. The results were in good agreement with certified values with precision of < 2.5% RSD. |
| 公开日期 | 2013-10-07 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/2099]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 青海盐湖研究所_盐湖资源与化学实验室 |
| 推荐引用方式 GB/T 7714 | Dong Ya-ping,Feng Hai-tao,Liu Xin,et al. Determination of Major, Minor Elements in the Samples of SrCO3 Productby X-Ray Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2009,29(8):2268-2271. |
| APA | Dong Ya-ping,Feng Hai-tao,Liu Xin,Meng Qing-fen,&Bian Shao-ju.(2009).Determination of Major, Minor Elements in the Samples of SrCO3 Productby X-Ray Fluorescence Spectrometry.SPECTROSCOPY AND SPECTRAL ANALYSIS,29(8),2268-2271. |
| MLA | Dong Ya-ping,et al."Determination of Major, Minor Elements in the Samples of SrCO3 Productby X-Ray Fluorescence Spectrometry".SPECTROSCOPY AND SPECTRAL ANALYSIS 29.8(2009):2268-2271. |
入库方式： OAI收割
来源：青海盐湖研究所
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