中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Effect of water and annealing temperature of anodized TiO2 nanotubes on hydrogen production in photoelectrochemical cell

文献类型:期刊论文

作者Li, Yongkun1,2; Yu, Hongmei1; Zhang, Changkun1,2; Song, Wei1; Li, Guangfu1,2; Shao, Zhigang1; Yi, Baolian1
刊名electrochimica acta
出版日期2013-09-30
卷号107页码:313-319
关键词Photoelectrochemical cell TiO2 nanotubes Morphology Annealing treatment Hydrogen production
产权排序1,1
通讯作者俞红梅
英文摘要an efficient and economical technology for hydrogen production via solar water splitting in a newly designed photoelectrochemical (pec) cell is reported. the core of the pec cell is a membrane electrode assembly (mea) that consisted of a tio2 nanotube photoanode, a pt/c cathode and alkaline membrane. the tio2 nanotube arrays (nts) were prepared by electrochemical anodization of titanium mesh in a mixed electrolyte solution of glycol and nh4f and then calcined at different temperature to transform the amorphous structure into crystalline. effect of water content on the morphology of the tio2nts is investigated, and the optimal amount of water in the electrolyte is between 10 wt% and 80 wt%. emphasis was the effect of the annealing temperature of anodized tio2nts on the hydrogen production in the pec cell. the results indicate that the crystal phase and morphology of tio2nts are stable at 450 degrees c, which exhibits the best photocatalytic activity. photocurrent generation of 1.55 ma/cm(2) under uv-light irradiation under applied bias (0.6 v vs. normal hydrogen electrode, nhe) shows good performance on hydrogen production. (c) 2013 elsevier ltd. all rights reserved.
WOS标题词science & technology ; physical sciences
学科主题物理化学
类目[WOS]electrochemistry
研究领域[WOS]electrochemistry
关键词[WOS]generation ; arrays ; cathode ; design ; light
收录类别SCI
语种英语
WOS记录号WOS:000326661200038
公开日期2013-10-11
源URL[http://159.226.238.44/handle/321008/117547]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Lab Fuel Cells, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Li, Yongkun,Yu, Hongmei,Zhang, Changkun,et al. Effect of water and annealing temperature of anodized TiO2 nanotubes on hydrogen production in photoelectrochemical cell[J]. electrochimica acta,2013,107:313-319.
APA Li, Yongkun.,Yu, Hongmei.,Zhang, Changkun.,Song, Wei.,Li, Guangfu.,...&Yi, Baolian.(2013).Effect of water and annealing temperature of anodized TiO2 nanotubes on hydrogen production in photoelectrochemical cell.electrochimica acta,107,313-319.
MLA Li, Yongkun,et al."Effect of water and annealing temperature of anodized TiO2 nanotubes on hydrogen production in photoelectrochemical cell".electrochimica acta 107(2013):313-319.

入库方式: OAI收割

来源:大连化学物理研究所

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