中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Electrochemical performances of spinel oxides as cathodes for intermediate temperature solid oxide fuel cells

文献类型:期刊论文

作者Liu, Huanying1,2; Zhu, Xuefeng1; Cheng, Mojie3; Cong, You1; Yang, Weishen1
刊名international journal of hydrogen energy
出版日期2013-01-24
卷号38期号:2页码:1052-1057
关键词Solid oxide fuel cells Spinel cathode Electrochemical performance (Mn Cu0.5MnCo1.5O4 Co)(3)O-4
产权排序1,1
通讯作者朱雪峰 ; 杨维慎
英文摘要the spinel-type oxides of (mn, co, cu)(3)o-4 prepared via a citric edta acid process were investigated as candidate cathodes of intermediate temperature solid oxide fuel cells (it-sofcs). (mn, co)(3)o-4 spinel oxide shows a phase transition from tetragonal to cubic when the doping amount of cobalt element increases. their electric conductivities increase with the cobalt content and are enough high for them used as cathodes of it-sofcs. a fuel cell with (mn, co)(3)o-4 spinel cathode was successfully evaluated based on ysz electrolyte. (mn, co)(3)o-4 spinel cathodes show good electrochemical activities, demonstrating the feasibility of the spinel oxide being a cathode of it-sofc. as copper doped into (mn, co)(3)o-4 spinel, the p-peak for cu0.5mnc1.5o4 cathode rise to 343, 474 and 506 mw cm(-2) at 700, 750 and 800 degrees c, respectively. the results reveal that the spinel-type oxides are promising cathodes for it-sofcs, especially for cu0.5mnco1.5o4. copyright (c) 2012, hydrogen energy publications, llc. published by elsevier ltd. all rights reserved.
WOS标题词science & technology ; physical sciences ; technology
学科主题物理化学
类目[WOS]chemistry, physical ; electrochemistry ; energy & fuels
研究领域[WOS]chemistry ; electrochemistry ; energy & fuels
关键词[WOS]sofc interconnect applications ; copper-manganese spinel ; oxygen reduction reaction ; electrical-properties ; resistant alloys ; oxidation ; electrocatalysts ; coatings
收录类别SCI
语种英语
WOS记录号WOS:000315001700034
公开日期2013-10-11
源URL[http://159.226.238.44/handle/321008/117574]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
3.Dalian Natl Lab Clean Energy, Div Fuel Cells, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Liu, Huanying,Zhu, Xuefeng,Cheng, Mojie,et al. Electrochemical performances of spinel oxides as cathodes for intermediate temperature solid oxide fuel cells[J]. international journal of hydrogen energy,2013,38(2):1052-1057.
APA Liu, Huanying,Zhu, Xuefeng,Cheng, Mojie,Cong, You,&Yang, Weishen.(2013).Electrochemical performances of spinel oxides as cathodes for intermediate temperature solid oxide fuel cells.international journal of hydrogen energy,38(2),1052-1057.
MLA Liu, Huanying,et al."Electrochemical performances of spinel oxides as cathodes for intermediate temperature solid oxide fuel cells".international journal of hydrogen energy 38.2(2013):1052-1057.

入库方式: OAI收割

来源:大连化学物理研究所

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