中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
High specific capacity of TiO2-graphene nanocomposite as an anode material for lithium-ion batteries in an enlarged potential window

文献类型:期刊论文

作者Cai, Dandan1; Lian, Peichao1; Zhu, Xuefeng2; Liang, Shuzhao1; Yang, Weishen2; Wang, Haihui1
刊名electrochimica acta
出版日期2012-07-15
卷号74页码:65-72
关键词Graphene TiO2 Nanocomposite Anode material Lithium-ion batteries
产权排序2, 3
通讯作者haihuiwang
英文摘要tio2-graphene nanocomposite was first synthesized by a facile gas/liquid interface reaction. the structure and morphology were characterized by x-ray diffraction, scanning electron microscopy, transmission electron microscopy, and brunauer-emmett-teller measurements. the results indicate that tio2 nanoparticles (ca. 10 nm in mean grain size) were successfully deposited onto the graphene sheets during the gas/liquid interfacial reaction process. the electrochemical performance was evaluated by using coin-type cells versus metallic lithium in an enlarged potential window of 0.01-3.0 v. a high specific charge capacity of 499 mah g(-1) was obtained at a current density of 100 ma g(-1). more strikingly, the tio2-graphene nanocomposite exhibits excellent rate capability, even at a high current density of 3000 ma g(-1), the specific charge capacity was still as high as 150 mah g(-1). the high specific charge capacities can be attributed to the facts that graphene possesses high electronic conductivity, and the lithium storage performance of graphene is delivered during discharge/charge processes of tio2-graphene nanocomposite between 0.01 and 3.0 v. (c) 2012 elsevier ltd. all rights reserved.
WOS标题词science & technology ; physical sciences
学科主题物理化学
类目[WOS]electrochemistry
研究领域[WOS]electrochemistry
关键词[WOS]superior electrode performance ; electrochemical performance ; cycling performance ; graphene nanosheets ; tio2 nanocrystals ; particle-size ; li storage ; anatase ; nanostructures ; composites
收录类别SCI
语种英语
WOS记录号WOS:000305373000010
公开日期2013-10-11
源URL[http://159.226.238.44/handle/321008/117695]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Cai, Dandan,Lian, Peichao,Zhu, Xuefeng,et al. High specific capacity of TiO2-graphene nanocomposite as an anode material for lithium-ion batteries in an enlarged potential window[J]. electrochimica acta,2012,74:65-72.
APA Cai, Dandan,Lian, Peichao,Zhu, Xuefeng,Liang, Shuzhao,Yang, Weishen,&Wang, Haihui.(2012).High specific capacity of TiO2-graphene nanocomposite as an anode material for lithium-ion batteries in an enlarged potential window.electrochimica acta,74,65-72.
MLA Cai, Dandan,et al."High specific capacity of TiO2-graphene nanocomposite as an anode material for lithium-ion batteries in an enlarged potential window".electrochimica acta 74(2012):65-72.

入库方式: OAI收割

来源:大连化学物理研究所

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