4-N,N-Dimethylaminopyridine Promoted Selective Oxidation of Methyl Aromatics with Molecular Oxygen
文献类型：期刊论文
| 作者 | Zhang, Zhan1,2; Gao, Jin1; Wang, Feng1; Xu, Jie1 |
| 刊名 | molecules
 |
| 出版日期 | 2012-04-01 |
| 卷号 | 17期号:4页码:3957-3968 |
| 关键词 | organocatalysis selective oxidation methyl aromatics molecular oxygen 4-N N-dimethylaminopyridine |
| 产权排序 | 1,1 |
| 通讯作者 | 徐杰 |
| 英文摘要 | 4-n,n-dimethylaminopyridine (dmap) as catalyst in combination with benzyl bromide was developed for the selective oxidation of methyl aromatics. dmap exhibited higher catalytic activity than other pyridine analogues, such as 4-carboxypyridine, 4-cyanopyridine and pyridine. the sp(3) hybrid carbon-hydrogen (c-h) bonds of different methyl aromatics were successfully oxygenated with molecular oxygen. the real catalyst is due to the formation of a pyridine onium salt from the bromide and dmap. the onium salt was well characterized by nmr and the reaction mechanism was discussed. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | catalyzed aerobic oxidation ; n-hydroxyphthalimide ; electron-transfer ; metal-free ; mild conditions ; hydrocarbons ; efficient ; bromide ; o-2 ; photooxidation |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000303309900027 |
| 公开日期 | 2013-10-11 |
| 源URL | [http://159.226.238.44/handle/321008/117701]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Zhan,Gao, Jin,Wang, Feng,et al. 4-N,N-Dimethylaminopyridine Promoted Selective Oxidation of Methyl Aromatics with Molecular Oxygen[J]. molecules,2012,17(4):3957-3968. |
| APA | Zhang, Zhan,Gao, Jin,Wang, Feng,&Xu, Jie.(2012).4-N,N-Dimethylaminopyridine Promoted Selective Oxidation of Methyl Aromatics with Molecular Oxygen.molecules,17(4),3957-3968. |
| MLA | Zhang, Zhan,et al."4-N,N-Dimethylaminopyridine Promoted Selective Oxidation of Methyl Aromatics with Molecular Oxygen".molecules 17.4(2012):3957-3968. |
入库方式： OAI收割
来源：大连化学物理研究所
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