Monoammoniate of Calcium Amidoborane: Synthesis, Structure, and Hydrogen-Storage Properties
文献类型：期刊论文
| 作者 | Chua, Yong Shen1,2; Wu, Hui3,4; Zhou, Wei3,4; Udovic, Terrence J.3; Wu, Guotao1; Xiong, Zhitao1; Wong, Ming Wah2; Chen, Ping1 |
| 刊名 | inorganic chemistry
 |
| 出版日期 | 2012-02-06 |
| 卷号 | 51期号:3页码:1599-1603 |
| 产权排序 | 1, 1 |
| 通讯作者 | huiwu ; 吴国涛 |
| 英文摘要 | the monoammoniate of calcium amidoborane, ca(nh2bh3)(2)center dot nh3, was synthesized by ball milling an equimolar mixture of canh and ab. its crystal structure has been determined and was found to contain a dihydrogen-bonded network. thermal decomposition under an open-system begins with the evolution of about 1 equivalent/formula unit (equiv.) of nh3 at temperatures <100 degrees c followed by the decomposition of ca(nh2bh3)(2) to release hydrogen. in a closed-system thermal decomposition process, hydrogen is liberated in two stages, at about 70 and 180 degrees c, with the first stage corresponding to an exothermic process. it has been found that the presence of the coordinated nh3 has induced the dehydrogenation to occur at low temperature. at the end of the dehydrogenation, about 6 equiv. (similar to 10.2 wt %) of hydrogen can be released, giving rise to the formation of cab2n3h. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, inorganic & nuclear |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | crystal-structure ; ammonia-borane ; thermal-decomposition ; metal amidoboranes ; release ; lithium ; amidotrihydroborate ; dehydrogenation ; alkali ; na |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000300474700052 |
| 公开日期 | 2013-10-11 |
| 源URL | [http://159.226.238.44/handle/321008/117771]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Natl Univ Singapore, Dept Chem, Singapore 117542, Singapore 3.NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA 4.Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA |
| 推荐引用方式 GB/T 7714 | Chua, Yong Shen,Wu, Hui,Zhou, Wei,et al. Monoammoniate of Calcium Amidoborane: Synthesis, Structure, and Hydrogen-Storage Properties[J]. inorganic chemistry,2012,51(3):1599-1603. |
| APA | Chua, Yong Shen.,Wu, Hui.,Zhou, Wei.,Udovic, Terrence J..,Wu, Guotao.,...&Chen, Ping.(2012).Monoammoniate of Calcium Amidoborane: Synthesis, Structure, and Hydrogen-Storage Properties.inorganic chemistry,51(3),1599-1603. |
| MLA | Chua, Yong Shen,et al."Monoammoniate of Calcium Amidoborane: Synthesis, Structure, and Hydrogen-Storage Properties".inorganic chemistry 51.3(2012):1599-1603. |
入库方式： OAI收割
来源：大连化学物理研究所
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