Role of boron-containing ionic liquid in the synthesis of manganese borophosphate with extra-large 16-ring pore openings
文献类型：期刊论文
| 作者 | Yang, Miao; Yan, Peifang; Xu, Feifei; Ma, Jianhua; Welz-Biermann, Urs |
| 刊名 | microporous and mesoporous materials
 |
| 出版日期 | 2012 |
| 卷号 | 147期号:1页码:73-78 |
| 关键词 | Extra-large microporous Metalloborophosphate Ionic liquid Crystal structure |
| 产权排序 | 1,1 |
| 通讯作者 | 杨淼 ; urswelzbiermann |
| 英文摘要 | an open-framework manganese borophosphate (nh(4))(7)mn(4)(h(2)o)[b(2)p(4)o(15)(oh)(2)](2)[h(2)po(4)][hpo(4)] (1) has been synthesized by using 1-butyl-3-methyl-imidazolium bis(oxalato)borate ([c(4)mim][bob]) ionic liquid as a boron source, and characterized by x-ray powder diffraction (xrd), inductively coupled plasma (icp), element analysis, thermogravimetric analysis and differential scanning calorimetry (tg-dsc). single-crystal x-ray diffraction analysis shows that compound 1 crystallizes in orthorhombic space group pnma (no. 62), a = 17.102(2) angstrom, b = 10.7195(15) angstrom, c = 22.283(3) angstrom, v = 4085.0(10) angstrom(3) and z = 4. its structure features an interrupted three-dimensional (3d) open-framework structure built up from [b(2)p(4)o(15)(oh)(2)](6-) borophosphate anions, mn(2)o(10) dimers and h(x)pw(4)(3-x) (x = 1, 2) groups, where peanut shaped extra-large 16-ring channels can be found extending along the [0 1 0] direction. protonated nh(3) molecules locate in the void space to balance the negative charges of the inorganic framework. magnetic measurements indicate that antiferromagnetic interactions exist between mn(2+) ions with a negative weiss constant of -18.2 k. the synthesis condition and various impact factors were studied carefully, which indicates that [bob] anion of ionic liquid and acidity of the system are two important keys for the formation of the title compound. (c) 2011 elsevier inc. all rights reserved. |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; science & technology - other topics ; materials science |
| 关键词[WOS] | ionothermal synthesis ; crystal-structure ; molecular-sieve ; framework ; zeolite ; aluminophosphate ; phosphite ; template ; solvent ; rings |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000295906200010 |
| 公开日期 | 2013-10-11 |
| 源URL | [http://159.226.238.44/handle/321008/117815]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, China Ion Liquid Lab, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Miao,Yan, Peifang,Xu, Feifei,et al. Role of boron-containing ionic liquid in the synthesis of manganese borophosphate with extra-large 16-ring pore openings[J]. microporous and mesoporous materials,2012,147(1):73-78. |
| APA | Yang, Miao,Yan, Peifang,Xu, Feifei,Ma, Jianhua,&Welz-Biermann, Urs.(2012).Role of boron-containing ionic liquid in the synthesis of manganese borophosphate with extra-large 16-ring pore openings.microporous and mesoporous materials,147(1),73-78. |
| MLA | Yang, Miao,et al."Role of boron-containing ionic liquid in the synthesis of manganese borophosphate with extra-large 16-ring pore openings".microporous and mesoporous materials 147.1(2012):73-78. |
入库方式： OAI收割
来源：大连化学物理研究所
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