The capability of characterizing arbitrary and non-repetitive emission spectra with a high resolution in real-time is of great merit in various research fields. Optical frequency combs provide precise and stable frequency grids for the measurement of a single spectral line with high accuracy. Particularly, dual-comb spectroscopy enables spectral measurement with a large bandwidth spanning tens of nanometers, but it is limited to measuring absorption spectra and has to trade-off spectral resolution vs the acquisition frame rate set by the repetition rate. Here, to alleviate these restrictions, we propose and demonstrate time-resolved spectroscopy for an emission spectrum based on hybrid asynchronous optical sampling, which features a spectral resolution of 0.63 pm, a frame rate of 1 MHz, and a measurement bandwidth of 13.6 nm, simultaneously. A mode-locked fiber comb with a repetition frequency of f(1 )is harnessed to interrogate emission spectral features with high resolution via optical Fourier transform achieved using a time-lens. Subsequently, a soliton microcomb of repetition frequency f(2s) asymptotic to 1000 f(1) serving as a probe pulse implements hybrid asynchronous optical sampling, thus significantly increasing the acquisition rate by nearly 3 orders of magnitude. As a proof-of-concept demonstration, the frequency trajectory of a rapidly scanning laser with a linear chirp of 6.2 THz/s is tracked. We believe that chip-scale microcombs will make the fast and high-resolution emission spectroscopy presented here a powerful tool for widespread applications. (C) 2022 Author(s)