Palladium-catalyzed selective oxidative olefination and arylation of 2-pyridones
文献类型：期刊论文
| 作者 | Chen, Yuye1,2; Wang, Fen1; Jia, Aiqun2; Li, Xingwei1 |
| 刊名 | chemical science
 |
| 出版日期 | 2012-11-01 |
| 卷号 | 3期号:11页码:3231-3236 |
| 产权排序 | 1,1 |
| 通讯作者 | 李兴伟 |
| 英文摘要 | substrate-controlled selective oxidative olefination of n-protected 2-pyridones has been achieved under palladium catalysis. the 5-position selectivity was followed for n-protected simple pyridones. introduction of substituents into the 4- or the 6-position switched the site selectivity to the 3-position. diolefination can also be achieved with high efficiency. oxidative arylation with polyfluorobenzenes followed a similar selectivity except that the system is more sterically and electronically demanding. |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | c-h functionalization ; carbon-hydrogen bonds ; intermolecular alkenylation ; simple arenes ; activation ; indoles ; polyfluoroarenes ; enamides ; derivatives ; enaminones |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000311068100016 |
| 公开日期 | 2013-10-11 |
| 源URL | [http://159.226.238.44/handle/321008/117869]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Nanjing Univ Sci & Technol, Sch Environm & Biol Engn, Nanjing 210014, Jiangsu, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Yuye,Wang, Fen,Jia, Aiqun,et al. Palladium-catalyzed selective oxidative olefination and arylation of 2-pyridones[J]. chemical science,2012,3(11):3231-3236. |
| APA | Chen, Yuye,Wang, Fen,Jia, Aiqun,&Li, Xingwei.(2012).Palladium-catalyzed selective oxidative olefination and arylation of 2-pyridones.chemical science,3(11),3231-3236. |
| MLA | Chen, Yuye,et al."Palladium-catalyzed selective oxidative olefination and arylation of 2-pyridones".chemical science 3.11(2012):3231-3236. |
入库方式： OAI收割
来源：大连化学物理研究所
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