The copolymerization reactivity of diols with 2,5-furandicarboxylic acid for furan-based copolyester materials
文献类型：期刊论文
| 作者 | Ma, Jiping1,2,3; Pang, Yi1; Wang, Min2,3; Xu, Jie2; Ma, Hong2; Nie, Xin2 |
| 刊名 | journal of materials chemistry
 |
| 出版日期 | 2012 |
| 卷号 | 22期号:8页码:3457-3461 |
| 产权排序 | 2,1 |
| 通讯作者 | 徐杰 |
| 英文摘要 | furan-based copolyesters were synthesized via polytransesterification of 2,5-furandicarboxylic acid (fdca) with ethylene glycol (eg) and 1,4-butylene glycol (bg). the composition and thermal properties of the obtained copolyesters were characterized in detail by h-1 nmr and elemental analysis, differential scanning calorimeters (dsc) and thermogravimetric analysis (tga). the h-1 nmr results showed that the ethylene segment content was consistently lower than that of butylene in the obtained copolyesters in comparison with the comonomer feeds. the reactivities of eg and bg with fdca were intensively investigated. on the basis of kinetic studies, eg was found to be less reactive than bg. the thermal properties of the obtained copolyesters could be adjusted by variation of the eg/bg molar ratios in the copolyesters. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, physical ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; materials science |
| 关键词[WOS] | aerobic oxidation ; comonomer reactivity ; efficient ; glycerol ; catalyst ; 2,5-diformylfuran ; hydrogenolysis ; dehydration ; polyester ; chemicals |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000299695400028 |
| 公开日期 | 2013-10-11 |
| 源URL | [http://159.226.238.44/handle/321008/117911]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Univ Akron, Dept Chem, Akron, OH 44325 USA 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, Jiping,Pang, Yi,Wang, Min,et al. The copolymerization reactivity of diols with 2,5-furandicarboxylic acid for furan-based copolyester materials[J]. journal of materials chemistry,2012,22(8):3457-3461. |
| APA | Ma, Jiping,Pang, Yi,Wang, Min,Xu, Jie,Ma, Hong,&Nie, Xin.(2012).The copolymerization reactivity of diols with 2,5-furandicarboxylic acid for furan-based copolyester materials.journal of materials chemistry,22(8),3457-3461. |
| MLA | Ma, Jiping,et al."The copolymerization reactivity of diols with 2,5-furandicarboxylic acid for furan-based copolyester materials".journal of materials chemistry 22.8(2012):3457-3461. |
入库方式： OAI收割
来源：大连化学物理研究所
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