Honeycomb-like nanocomposite Ti-Ag-N films prepared by pulsed bias arc ion plating on titanium as bipolar plates for unitized regenerative fuel cells
文献类型：期刊论文
| 作者 | Zhang, Min1,2; Hu, Lin3; Lin, Guoqiang3; Shao, Zhigang2 |
| 刊名 | journal of power sources
 |
| 出版日期 | 2012-01-15 |
| 卷号 | 198期号:15页码:196-202 |
| 关键词 | Nanocomposite thin film Ti-Ag-N Pulsed bias arc ion plating Bipolar plate Unitized regenerative fuel cell |
| 产权排序 | 1,1 |
| 通讯作者 | 张敏 ; 邵志刚 |
| 英文摘要 | honeycomb-like nanocomposite ti-ag-n films are prepared by pulsed bias arc ion plating, and for the first time served as surface modification layer on ta1 titanium as bipolar plates for unitized regenerative fuel cells (urfcs). phase structure and surface morphology of the coated samples are investigated by xrd and sem. corrosion resistance of bare ti plates and ti-ag-n coated samples is evaluated in simulated urfc conditions, and the interface contact resistance (icr) between bipolar plates and carbon papers is measured before and after potentiostatic polarization tests. ti2n phase with a preferred orientation of (1 1 0) plane is observed in the ti-ag-n film. sem observation indicates that the film appears honeycomb-like and forms a nanocomposite microstructure with ag nanoparticles embedded in ti2n matrix. compared to bare titanium plates, the coated sample shows improved corrosion resistance and ultra-low icr (2 m omega cm(2) under a compaction pressure of 1.4 mpa). the superior conductivity of the coated sample is attributed to nanocomposite microstructure containing highly conductive ag nanoparticles, and honeycomb-like rough surface obtained in this study. nanocomposite ti-ag-n coated titanium bipolar plate exhibits prominent interfacial conductivity and excellent corrosion resistance at high potential, being a promising candidate as bipolar plate for applications in urfcs. (c) 2011 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | electrochemistry ; energy & fuels |
| 研究领域[WOS] | electrochemistry ; energy & fuels |
| 关键词[WOS] | interfacial contact resistance ; 316l stainless-steel ; membrane ; surface ; corrosion ; performance ; coatings |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000297890700030 |
| 公开日期 | 2013-10-11 |
| 源URL | [http://159.226.238.44/handle/321008/117913]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Liaoning Normal Univ, Sch Phys & Elect Technol, Dalian 116029, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Fuel Cell R&D Ctr, Dalian 116023, Peoples R China 3.Dalian Univ Technol, Lab Mat Modificat Laser Ion & Electron Beams, Dalian 116085, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Min,Hu, Lin,Lin, Guoqiang,et al. Honeycomb-like nanocomposite Ti-Ag-N films prepared by pulsed bias arc ion plating on titanium as bipolar plates for unitized regenerative fuel cells[J]. journal of power sources,2012,198(15):196-202. |
| APA | Zhang, Min,Hu, Lin,Lin, Guoqiang,&Shao, Zhigang.(2012).Honeycomb-like nanocomposite Ti-Ag-N films prepared by pulsed bias arc ion plating on titanium as bipolar plates for unitized regenerative fuel cells.journal of power sources,198(15),196-202. |
| MLA | Zhang, Min,et al."Honeycomb-like nanocomposite Ti-Ag-N films prepared by pulsed bias arc ion plating on titanium as bipolar plates for unitized regenerative fuel cells".journal of power sources 198.15(2012):196-202. |
入库方式： OAI收割
来源：大连化学物理研究所
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