Enhanced hydrothermal stability of high performance lean fuel combustion alumina-supported palladium catalyst modified by nickel
文献类型：期刊论文
| 作者 | Liu, Ying1,2; Wang, Sheng1; Sun, Tianjun1; Gao, Diannan1; Zhang, Chunxi1; Wang, Shudong1 |
| 刊名 | applied catalysis b-environmental
 |
| 出版日期 | 2012-05-30 |
| 卷号 | 119页码:321-328 |
| 关键词 | Ventilation air methane combustion Palladium NiAl2O4 spinel Lattice mismatch |
| 产权排序 | 1,1 |
| 通讯作者 | 王树东 |
| 英文摘要 | the hydrothermal stability of pd-based methane combustion catalyst was investigated under lean-fuel conditions, such as ventilation air methane. for the catalyst, the active component pd was impregnated on ni-modified alumina supports which were prepared by a modified method. the method was coupled with the conventional co-precipitation and hydrothermal synthesis process. a series of pd catalysts and supports prepared, which had the ni/al ratios of 1:4, 1:2 and 1:1, were characterized by bet, co-chemisorption, xrd, tpr, sem and tem. the relationship between active sites and supports was studied using hrtem. in addition, the performances for lean methane combustion of all catalysts were studied. results showed that the catalyst on well crystallized nial2o4 spinet support exhibited the superior hydrothermal stability. methane conversion remained 96% after 3200 h at 873 k. such excellent catalytic performance has been validated to relate to the stabilizing effect of support and the least lattice mismatch between nial2o4 and pd, which contributed to high pd dispersion. (c) 2012 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, physical ; engineering, environmental ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | gas engine exhaust ; methane combustion ; low-temperature ; complete oxidation ; pd catalysts ; thermal-stability ; water ; behavior ; oxide ; ni |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000304691700038 |
| 公开日期 | 2013-10-11 |
| 源URL | [http://159.226.238.44/handle/321008/117936]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Ying,Wang, Sheng,Sun, Tianjun,et al. Enhanced hydrothermal stability of high performance lean fuel combustion alumina-supported palladium catalyst modified by nickel[J]. applied catalysis b-environmental,2012,119:321-328. |
| APA | Liu, Ying,Wang, Sheng,Sun, Tianjun,Gao, Diannan,Zhang, Chunxi,&Wang, Shudong.(2012).Enhanced hydrothermal stability of high performance lean fuel combustion alumina-supported palladium catalyst modified by nickel.applied catalysis b-environmental,119,321-328. |
| MLA | Liu, Ying,et al."Enhanced hydrothermal stability of high performance lean fuel combustion alumina-supported palladium catalyst modified by nickel".applied catalysis b-environmental 119(2012):321-328. |
入库方式： OAI收割
来源：大连化学物理研究所
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