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The Role of NMR in Metal Organic Frameworks: Deep Insights into Dynamics, Structure and Mapping of Functional Groups

文献类型：期刊论文

作者Rehman, Sajid Ur4; Xu, Shuai1,4; Xu, Huangtao4; Tao, Tongxiang4,5; Li, Yunyan4; Yu, Zhiwu4; Ma, Kun4; Xu, Weihong2; Wang, Junfeng3,4,5
刊名MATERIALS TODAY ADVANCES
出版日期2022-12-01
卷号16
关键词Metal organic frameworks NMR mapping of functional groups host-guest interaction
ISSN号2590-0498
DOI10.1016/j.mtadv.2022.100287
通讯作者Ma, Kun(makun@hmfl.ac.cn) ; Wang, Junfeng(junfeng@hmfl.ac.cn)
英文摘要The fundamental understanding of metal-organic frameworks (MOFs) is crucial since the relationship between the macroscopic properties of these materials and their molecular-level structures allows for the development of technological applications and improvements in current performance. The metal centers and attached functional groups dictate MOFs' dynamics, structure, and porosity. The develop-ment of the solid-state nuclear magnetic resonance (SSNMR) technique, capable of providing atomic -level information, enables the non-destructive characterization of the structure and dynamics of MOFs have become essential step in ameliorating our understanding and are often complementary to tradi-tional methods. This review aims to briefly introduce the concepts of SSNMR and the methods employed when investigating the dynamics, structure, and mapping of functional groups of microporous materials, including MOFs. This review highlights the best experimental practices when working with these complex systems. The article scrutinizes the information on framework structures, active center, surface position, host-guest interaction, and intermediate interaction through different SSNMR spectrums. Despite all the recent technological advancements, the SSNMR still faces the challenges of large sample quantities, long experimental measurements and data analyses, and complex isotopic labeling, which are enlightened in this review.(c) 2022 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
WOS关键词SOLID-STATE NMR ; O-17 NMR ; SPECTROSCOPY ; MOLECULES ; TRANSFORMATION ; TRANSITION ; STABILITY ; CHEMISTRY ; PROTEINS ; BINDING
资助项目National Natural Science Foundation of China[3190110313] ; National Natural Science Foundation of China[42177444] ; National Natural Science Foundation of China[U1932218] ; Chinese Academy of Sciences[YZJJ2022QN44] ; Alliance of International Science Organizations[ANSO-VF-2021-03] ; HFIPS Director's Fund[YZJJZX202014]
WOS研究方向Materials Science
语种英语
WOS记录号WOS:000860494200002
出版者ELSEVIER
资助机构National Natural Science Foundation of China ; Chinese Academy of Sciences ; Alliance of International Science Organizations ; HFIPS Director's Fund
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/129135]  
专题中国科学院合肥物质科学研究院
通讯作者Ma, Kun; Wang, Junfeng
作者单位1.Chinese Acad Sci, Hefei Canc Hosp, Inst Hlth & Med Technol, Anhui Prov Key Lab Med Phys & Technol,Hefei Inst P, Hefei 230031, Anhui, Peoples R China
2.Chinese Acad Sci, Inst Intelligent Machines, Hefei Inst Phys Sci, Anhui Prov Key Lab Biomimet Sensing & Adv Robot Te, Hefei 230031, Peoples R China
3.Anhui Univ, Inst Phys Sci & Informat Technol, Hefei 230601, Anhui, Peoples R China
4.Chinese Acad Sci, Hefei Inst Phys Sci, CAS Key Lab High Magnet Field & Ion Beam Phys Biol, Hefei 230031, Anhui, Peoples R China
5.Univ Sci & Technol China, Hefei 230036, Anhui, Peoples R China
推荐引用方式
GB/T 7714		 Rehman, Sajid Ur,Xu, Shuai,Xu, Huangtao,et al. The Role of NMR in Metal Organic Frameworks: Deep Insights into Dynamics, Structure and Mapping of Functional Groups[J]. MATERIALS TODAY ADVANCES,2022,16.
APA Rehman, Sajid Ur.,Xu, Shuai.,Xu, Huangtao.,Tao, Tongxiang.,Li, Yunyan.,...&Wang, Junfeng.(2022).The Role of NMR in Metal Organic Frameworks: Deep Insights into Dynamics, Structure and Mapping of Functional Groups.MATERIALS TODAY ADVANCES,16.
MLA Rehman, Sajid Ur,et al."The Role of NMR in Metal Organic Frameworks: Deep Insights into Dynamics, Structure and Mapping of Functional Groups".MATERIALS TODAY ADVANCES 16(2022).

入库方式： OAI收割

来源：合肥物质科学研究院

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