Investigation of Chlorine-initiated Oxidation Reactions of Nopinone by Vacuum Ultraviolet Photoionization Mass Spectrometry
文献类型：期刊论文
| 作者 | Hu Rong-Rong1,2; Ma Zi-Ji1,2; Yue Hao1,2; Lin Xiao-Xiao2 ; Wen Zuo-Ying2; Zhang Wei-Jun2; Gu Xue-Jun2; Tang Xiao-Feng2
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| 刊名 | CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
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| 出版日期 | 2022-06-01 |
| 卷号 | 50 |
| ISSN号 | 0253-3820 |
| 关键词 | Nopinone Chlorine atom Photoionization mass spectrometry Oxidation reaction mechanism Peroxy radicals |
| DOI | 10.19756/j.issn.0253-3820.221081 |
| 通讯作者 | Lin Xiao-Xiao(lxx1989@aiofm.ac.cn) |
| 英文摘要 | A microwave discharge fast flow tube reactor was used to simulate chlorine- initiated oxidation of nopinone(C9H14O). The chemical compositions of radicals and stable products from the oxidation reactions were measured via a home-made vacuum ultraviolet photoionization time of flight mass spectrometer(VUVPI-TOFMS). The kinetic experiments of main radicals and products were also performed. By comparing the results of kinetic experiments and simulation calculations of key species, the reaction pathways of key species in the reaction were further explored. This study showed that the reaction of nopinone with Cl produced radical C9H13O via the hydrogen abstraction pathway. The radical C9H13O reacted with O-2 to mainly generate peroxy radical C9H13OO2. Under NOx(NO and NO2)free condition, peroxy radical C9H13OO2 reacted with itself to produce radical C9H13OO, carbonyl compounds C9H13OO2 and C9H13OOH. In addition, the peroxy radical C9H13OO2 could also react with HO2 to produce hydroperoxide C9H13OO2H. The mechanism of chlorine-initiated oxidation reactions of nopinone was also revealed through experimental studies and simulation calcu lations. |
| WOS关键词 | VOLATILE ORGANIC-COMPOUNDS ; GAS-PHASE REACTIONS ; BETA-PINENE ; ATMOSPHERIC CHEMISTRY ; ALKYLPEROXY RADICALS ; PLUS O-2 ; OH ; STABILITY ; LASER |
| 资助项目 | National Natural Science Foundation of China[42075113] ; National Natural Science Foundation of China[42120104007] ; National Natural Science Foundation of China[91961123] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | SCIENCE PRESS |
| WOS记录号 | WOS:000884100200018 |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/130106]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 通讯作者 | Lin Xiao-Xiao |
| 作者单位 | 1.Univ Sci & Technol China, Sci Isl Branch, Grad Sch, Hefei 230026, Peoples R China 2.Chinese Acad Sci, Anhui Inst Opt & Fine Mech, Hefei Inst Phys Sci, Hefei 230031, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu Rong-Rong,Ma Zi-Ji,Yue Hao,et al. Investigation of Chlorine-initiated Oxidation Reactions of Nopinone by Vacuum Ultraviolet Photoionization Mass Spectrometry[J]. CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,2022,50. |
| APA | Hu Rong-Rong.,Ma Zi-Ji.,Yue Hao.,Lin Xiao-Xiao.,Wen Zuo-Ying.,...&Tang Xiao-Feng.(2022).Investigation of Chlorine-initiated Oxidation Reactions of Nopinone by Vacuum Ultraviolet Photoionization Mass Spectrometry.CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,50. |
| MLA | Hu Rong-Rong,et al."Investigation of Chlorine-initiated Oxidation Reactions of Nopinone by Vacuum Ultraviolet Photoionization Mass Spectrometry".CHINESE JOURNAL OF ANALYTICAL CHEMISTRY 50(2022). |
入库方式： OAI收割
来源：合肥物质科学研究院
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