Rhodium(III)-catalyzed oxidative mono- and di-olefination of isonicotinamides
文献类型：期刊论文
| 作者 | Wei, Xiaohong1,2; Wang, Feng1; Song, Guoyong1; Du, Zhengyin2; Li, Xingwei1 |
| 刊名 | organic & biomolecular chemistry
 |
| 出版日期 | 2012 |
| 卷号 | 10期号:29页码:5521-5524 |
| 产权排序 | 1,1 |
| 通讯作者 | 李兴伟 |
| 英文摘要 | [rhcp*cl-2](2) can catalyze the oxidative coupling of secondary isonicotinamides with activated olefins using cu(oac)(2) as an oxidant. the selectivity can be controlled by the solvent. in mecn, the mono-olefination and two-fold oxidation reaction is the major pathway, while in thf this reaction gave mostly diolefination products. in both cases, the coupled products contain an exocyclic c=c bond. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | c-h bond ; stereoselective-synthesis ; internal alkynes ; acid derivatives ; benzoic-acids ; activation ; alkenes ; arylation ; cleavage ; coupling/cyclization |
| 收录类别 | SCI ; IC ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000305965400005 |
| 公开日期 | 2013-10-11 |
| 源URL | [http://159.226.238.44/handle/321008/118058]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.NW Normal Univ, Coll Chem & Chem Engn, Lanzhou 730070, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wei, Xiaohong,Wang, Feng,Song, Guoyong,et al. Rhodium(III)-catalyzed oxidative mono- and di-olefination of isonicotinamides[J]. organic & biomolecular chemistry,2012,10(29):5521-5524. |
| APA | Wei, Xiaohong,Wang, Feng,Song, Guoyong,Du, Zhengyin,&Li, Xingwei.(2012).Rhodium(III)-catalyzed oxidative mono- and di-olefination of isonicotinamides.organic & biomolecular chemistry,10(29),5521-5524. |
| MLA | Wei, Xiaohong,et al."Rhodium(III)-catalyzed oxidative mono- and di-olefination of isonicotinamides".organic & biomolecular chemistry 10.29(2012):5521-5524. |
入库方式： OAI收割
来源：大连化学物理研究所
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