Preparation of copper (II) ion-containing bisimidazolium ionic liquid bridged periodic mesoporous organosilica and the catalytic decomposition of cyclohexyl hydroperoxide
文献类型：期刊论文
| 作者 | Zheng, Xi1,2; Wang, Min1,2; Sun, Zhiqiang1; Chen, Chen1; Ma, Jiping1; Xu, Jie1 |
| 刊名 | catalysis communications
 |
| 出版日期 | 2012-12-05 |
| 卷号 | 29页码:149-152 |
| 关键词 | Bisimidazolium ionic liquids Periodic mesoporous organosilica Copper Cyclohexyl hydroperoxide Decomposition |
| 产权排序 | 1,1 |
| 通讯作者 | 徐杰 |
| 英文摘要 | a novel bisimidazolium ionic liquid bridged periodic mesoporous organosilica was prepared. bisimidazolium ionic liquid was incorporated into the framework of mesoporous materials and copper (ii) chloride can be easily introduced to the framework via the formation of cucl42- complex. this copper (ii) ion-containing bisimidazolium ionic liquid bridged material showed high activity and stability in the decomposition of cyclohexyl hydroperoxide. ninety-nine percent conversion and 84% selectivity for cyclohexanone and cyclohexanol (k/a oil) could be obtained. (c) 2012 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | oxidation ; efficient ; water ; deperoxidation ; complexes ; framework ; chlorides ; walls ; pmos |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000313024300032 |
| 公开日期 | 2013-10-11 |
| 源URL | [http://159.226.238.44/handle/321008/118065]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng, Xi,Wang, Min,Sun, Zhiqiang,et al. Preparation of copper (II) ion-containing bisimidazolium ionic liquid bridged periodic mesoporous organosilica and the catalytic decomposition of cyclohexyl hydroperoxide[J]. catalysis communications,2012,29:149-152. |
| APA | Zheng, Xi,Wang, Min,Sun, Zhiqiang,Chen, Chen,Ma, Jiping,&Xu, Jie.(2012).Preparation of copper (II) ion-containing bisimidazolium ionic liquid bridged periodic mesoporous organosilica and the catalytic decomposition of cyclohexyl hydroperoxide.catalysis communications,29,149-152. |
| MLA | Zheng, Xi,et al."Preparation of copper (II) ion-containing bisimidazolium ionic liquid bridged periodic mesoporous organosilica and the catalytic decomposition of cyclohexyl hydroperoxide".catalysis communications 29(2012):149-152. |
入库方式： OAI收割
来源：大连化学物理研究所
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