中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Crystal-Phase- and Morphology-Controlled Synthesis of Fe2O3 Nanomaterials

文献类型:期刊论文

作者Mou, Xiaoling1; Li, Yong1; Zhang, Bingsen2; Yao, Lide3; Wei, Xuejiao1; Su, Dang Sheng2,3; Shen, Wenjie1
刊名european journal of inorganic chemistry
出版日期2012-06-01
期号16页码:2684-2690
关键词Crystal phase Morphology Iron Nanostructures Surface analysis
产权排序1,1
通讯作者dangshengsu ; 申文杰
英文摘要a- and ?-fe2o3 nanorods have been prepared from a beta-feooh precursor that was obtained by aqueous-phase precipitation of ferric chloride. the oxyhydroxide precursor had a rodlike shape with a diameter of 30-40 nm and a length of 400-500 nm. calcination at 500 degrees c of the rod-shaped oxyhydroxide in air yielded a-fe2o3 nanorods, whereas heating to reflux in polyethylene glycol (peg) at 200 degrees c resulted in the formation of ?-fe2o3 nanorods. both oxides inherited the rodlike morphology of the precursor but exposed different crystalline facets. when being used to catalyze no reduction by co, an environmentally important reaction in no abatement, the ?-fe2o3 nanorods were much more active than the a-fe2o3 nanorods and showed an apparent crystal-phase effect. this was because the ?-fe2o3 nanorods simultaneously exposed iron and oxygen ions on their surfaces, which facilitated the adsorption and activation of no and co molecules.
WOS标题词science & technology ; physical sciences
学科主题物理化学
类目[WOS]chemistry, inorganic & nuclear
研究领域[WOS]chemistry
关键词[WOS]iron-oxide ; beta-feooh ; alpha-fe2o3 nanorods ; magnetic-properties ; gamma-fe2o3 nanoparticles ; carbon-monoxide ; no oxidation ; co reaction ; hematite ; reduction
收录类别SCI
语种英语
WOS记录号WOS:000304089700014
公开日期2013-10-11
源URL[http://159.226.238.44/handle/321008/118231]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Peoples R China
3.Max Planck Gesell, Fritz Haber Inst, Dept Inorgan Chem, D-14195 Berlin, Germany
推荐引用方式
GB/T 7714
Mou, Xiaoling,Li, Yong,Zhang, Bingsen,et al. Crystal-Phase- and Morphology-Controlled Synthesis of Fe2O3 Nanomaterials[J]. european journal of inorganic chemistry,2012(16):2684-2690.
APA Mou, Xiaoling.,Li, Yong.,Zhang, Bingsen.,Yao, Lide.,Wei, Xuejiao.,...&Shen, Wenjie.(2012).Crystal-Phase- and Morphology-Controlled Synthesis of Fe2O3 Nanomaterials.european journal of inorganic chemistry(16),2684-2690.
MLA Mou, Xiaoling,et al."Crystal-Phase- and Morphology-Controlled Synthesis of Fe2O3 Nanomaterials".european journal of inorganic chemistry .16(2012):2684-2690.

入库方式: OAI收割

来源:大连化学物理研究所

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