BODIPY derivatives as n-type organic semiconductors: Isomer effect on carrier mobility
文献类型：期刊论文
| 作者 | Zhang, Ming-Xing; Chai, Shuo; Zhao, Guang-Jiu |
| 刊名 | organic electronics
 |
| 出版日期 | 2012-02-01 |
| 卷号 | 13期号:2页码:215-221 |
| 关键词 | Carrier mobility Organic semiconductor BODIPY Electron transfer Isomer effect Anisotropic behavior |
| 产权排序 | 1,1 |
| 通讯作者 | 赵广久 |
| 英文摘要 | in the present work, two dipyrro-boradiazaindacenes (bodipy) derivatives functioning as novel high-performance organic semiconductors are investigated by theoretical method. these two isomeric complexes are demonstrated to have large electron-transfer mobility, which means they are favor to be n-type organic semiconductors. the highest electron-transfer mobility appears at the same packing style in two crystals. the intermolecular distances of the packing style are nearly same, 4.994 angstrom in crystal 1 and 5.283 angstrom in crystal 2. however, their electron-transfer mobility changes significantly. the mobility of crystal 2 with better planar molecular structure is 0.291 cm(2) v-1 s(-1), which is 13 times larger than that of crystal 1 as 0.022 cm(2) v-1 s(-1). the significant difference of carrier mobility is ascribed to the little structural difference of these two isomers. it has been demonstrated that both crystal 1 and 2 show remarkable anisotropic behavior. this study will undoubtedly provide a new understanding of isomerization on designing novel organic semiconductors. (c) 2011 elsevier b. v. all rights reserved. |
| WOS标题词 | science & technology ; technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | materials science, multidisciplinary ; physics, applied |
| 研究领域[WOS] | materials science ; physics |
| 关键词[WOS] | charge-transport properties ; field-effect mobility ; energy-transfer ; reorganization energy ; effect transistors ; electron-transfer ; single-crystals ; hole mobilities ; pentacene ; polarization |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000299539100001 |
| 公开日期 | 2013-10-11 |
| 源URL | [http://159.226.238.44/handle/321008/118246]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Ming-Xing,Chai, Shuo,Zhao, Guang-Jiu. BODIPY derivatives as n-type organic semiconductors: Isomer effect on carrier mobility[J]. organic electronics,2012,13(2):215-221. |
| APA | Zhang, Ming-Xing,Chai, Shuo,&Zhao, Guang-Jiu.(2012).BODIPY derivatives as n-type organic semiconductors: Isomer effect on carrier mobility.organic electronics,13(2),215-221. |
| MLA | Zhang, Ming-Xing,et al."BODIPY derivatives as n-type organic semiconductors: Isomer effect on carrier mobility".organic electronics 13.2(2012):215-221. |
入库方式： OAI收割
来源：大连化学物理研究所
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