Copper(II)-Mediated Dehydrogenative Cross-Coupling of Heteroarenes
文献类型:期刊论文
| 作者 | Mao, Zhifeng1; Wang, Zhe2; Xu, Zhaoqing1,2; Huang, Fei1; Yu, Zhengkun1; Wang, Rui2 |
| 刊名 | organic letters
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| 出版日期 | 2012-08-03 |
| 卷号 | 14期号:15页码:3854-3857 |
| 产权排序 | 1,1 |
| 通讯作者 | 许兆青 ; 余正坤 ; ruiwang |
| 英文摘要 | cu(oac)(2)-mediated dehydrogenative cross-coupling between two heteroarenes has been realized in the absence of any other additive. a mechanism involving a formal cu(ii) to cu(0) route by convergent disproportionation of the copper mediator is proposed and has been evidenced by copper mirror formation during the reaction. this synthetic protocol provides a concise and "green" access to unsymmetrical biheteroarenes bearing structural motifs of substantial utility in organic synthesis. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | c-h bonds ; copper-catalyzed arylation ; general-method ; aryl bromides ; sole oxidant ; palladium ; azoles ; functionalizations ; heterocycles ; acids |
| 收录类别 | SCI ; IC ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000307041600011 |
| 公开日期 | 2013-10-11 |
| 源URL | [http://159.226.238.44/handle/321008/118247] ![]() |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Lanzhou Univ, Key Lab Preclin Study New Drugs Gansu Prov, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Mao, Zhifeng,Wang, Zhe,Xu, Zhaoqing,et al. Copper(II)-Mediated Dehydrogenative Cross-Coupling of Heteroarenes[J]. organic letters,2012,14(15):3854-3857. |
| APA | Mao, Zhifeng,Wang, Zhe,Xu, Zhaoqing,Huang, Fei,Yu, Zhengkun,&Wang, Rui.(2012).Copper(II)-Mediated Dehydrogenative Cross-Coupling of Heteroarenes.organic letters,14(15),3854-3857. |
| MLA | Mao, Zhifeng,et al."Copper(II)-Mediated Dehydrogenative Cross-Coupling of Heteroarenes".organic letters 14.15(2012):3854-3857. |
入库方式: OAI收割
来源:大连化学物理研究所
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