Chiral Tridentate P,N,N Ligands for Highly Enantioselective Copper-Catalyzed Propargylic Amination with both Primary and Secondary Amines as Nucleophiles
文献类型：期刊论文
| 作者 | Zhang, Cheng1,2; Wang, Ya-Hui1; Hu, Xin-Hu1; Zheng, Zhuo1; Xu, Jie1; Hu, Xiang-Ping1 |
| 刊名 | advanced synthesis & catalysis
 |
| 出版日期 | 2012-10-01 |
| 卷号 | 354期号:14-15页码:2854-2858 |
| 关键词 | asymmetric catalysis copper primary amines propargylic amination secondary amines |
| 产权排序 | 1,1 |
| 通讯作者 | 胡向平 |
| 英文摘要 | chiral tridentate p,n,n ligands have been demonstrated to be highly efficient for the copper-catalyzed enantioselective propargylic amination of propargylic acetates with both primary and secondary amines as nucleophiles, affording the corresponding propargylic amines in high yields and with excellent enantioselectivities (up to 97% ee for secondary amines, and up to 96% ee for primary amines). furthermore, the present catalytic system was also effective for the more challenging aliphatic propargylic acetate substrates. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, applied ; chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | asymmetric alkynylation ; substitution-reactions ; carbonyl groups ; imines ; alkynes ; esters ; additions ; access |
| 收录类别 | SCI ; IC ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000309907300035 |
| 公开日期 | 2013-10-11 |
| 源URL | [http://159.226.238.44/handle/321008/118266]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Cheng,Wang, Ya-Hui,Hu, Xin-Hu,et al. Chiral Tridentate P,N,N Ligands for Highly Enantioselective Copper-Catalyzed Propargylic Amination with both Primary and Secondary Amines as Nucleophiles[J]. advanced synthesis & catalysis,2012,354(14-15):2854-2858. |
| APA | Zhang, Cheng,Wang, Ya-Hui,Hu, Xin-Hu,Zheng, Zhuo,Xu, Jie,&Hu, Xiang-Ping.(2012).Chiral Tridentate P,N,N Ligands for Highly Enantioselective Copper-Catalyzed Propargylic Amination with both Primary and Secondary Amines as Nucleophiles.advanced synthesis & catalysis,354(14-15),2854-2858. |
| MLA | Zhang, Cheng,et al."Chiral Tridentate P,N,N Ligands for Highly Enantioselective Copper-Catalyzed Propargylic Amination with both Primary and Secondary Amines as Nucleophiles".advanced synthesis & catalysis 354.14-15(2012):2854-2858. |
入库方式： OAI收割
来源：大连化学物理研究所
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