Heat capacities and thermodynamic properties of N-(tert-butoxycarbonyl)-L-phenylalanine (C14H19NO4)
文献类型：期刊论文
| 作者 | Zhao, Z. -M.3; Sun, L. -X.3; Tan, Z. -C.1,2 |
| 刊名 | journal of thermal analysis and calorimetry
 |
| 出版日期 | 2012-03-01 |
| 卷号 | 107期号:3页码:1315-1319 |
| 关键词 | Heat capacity Thermodynamic property N-(tert-butoxycarbonyl)-L-phenylalanine |
| 产权排序 | 1,1 |
| 通讯作者 | 谭志诚 |
| 英文摘要 | the heat capacities of n-(tert-butoxycarbonyl)-l- phenylalanine (abbreviated to ntblp in this article), as an important chemical intermediates used to synthesize proteins and polypeptides, were measured by means of a fully automated adiabatic calorimeter over the temperature range from 78 to 350 k. the measured experimental heat capacities were fitted to a polynomial equation as a function of temperature. the thermodynamic functions, h-t - h-298.15k and s-t - s-298.15k, were calculated based on the heat capacity polynomial equation in the temperature range of (80-350 k) with an interval of 5 k. the thermal stability of the compound was further studied using tg and dsc analyses; a possible mechanism for thermal decomposition of the compound was suggested. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, analytical ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | adiabatic calorimeter ; small samples |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000302703400058 |
| 公开日期 | 2013-10-11 |
| 源URL | [http://159.226.238.44/handle/321008/118377]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, China Ion Liquid Lab, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China 3.Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Z. -M.,Sun, L. -X.,Tan, Z. -C.. Heat capacities and thermodynamic properties of N-(tert-butoxycarbonyl)-L-phenylalanine (C14H19NO4)[J]. journal of thermal analysis and calorimetry,2012,107(3):1315-1319. |
| APA | Zhao, Z. -M.,Sun, L. -X.,&Tan, Z. -C..(2012).Heat capacities and thermodynamic properties of N-(tert-butoxycarbonyl)-L-phenylalanine (C14H19NO4).journal of thermal analysis and calorimetry,107(3),1315-1319. |
| MLA | Zhao, Z. -M.,et al."Heat capacities and thermodynamic properties of N-(tert-butoxycarbonyl)-L-phenylalanine (C14H19NO4)".journal of thermal analysis and calorimetry 107.3(2012):1315-1319. |
入库方式： OAI收割
来源：大连化学物理研究所
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