Study on the Morphologies of Covalent Organic Microporous Polymers: the Role of Reaction Solvents
文献类型：期刊论文
| 作者 | Tan, Dazhi1; Fan, Wenjie2; Xiong, Wannan1; Sun, Hanxue3; Cheng, Yaqi1; Liu, Xiaoyu1; Meng, Changgong1; Li, An3; Deng, Wei-Qiao2 |
| 刊名 | macromolecular chemistry and physics
 |
| 出版日期 | 2012-07-26 |
| 卷号 | 213期号:14页码:1435-1440 |
| 关键词 | conjugated polymers morphology networks organic solvents storage two dimension |
| ISSN号 | 1022-1352 |
| 产权排序 | 2,2 |
| 通讯作者 | changgongmeng ; anli ; 邓伟侨 |
| 英文摘要 | two-dimensional conjugated microporous polymers (cmps) composed of alternative phenylene and ethynylene units are synthesized, by cross-coupling polymerization of 1,3,5-triethynylbenzene and 1,3,5-tribromobenzene with various solvents. our work shows that the morphology of cmps is greatly affected by the choice of solvents used in synthesis. sphere, tubular, and plate-like structures are received by using the toluene, p-xylene, and mesitylene solvents, respectively. our results demonstrate that the morphology of cmps affects the storage capacity for organic solvents remarkably, with the plate-like cmp showing best performance. this work is expected to provide useful guidance to rationally design cmps as absorbent materials for organic solvents. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | polymer science |
| 研究领域[WOS] | polymer science |
| 关键词[WOS] | triazine-based frameworks ; surface-area ; intrinsic microporosity ; networks ; macrocycles ; porosity ; films |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000306406100003 |
| 公开日期 | 2013-10-11 |
| 源URL | [http://159.226.238.44/handle/321008/118416]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Univ Technol, Expt Ctr Chem, Fac Chem Environm & Biol Sci & Technol, Dalian 116024, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China 3.Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tan, Dazhi,Fan, Wenjie,Xiong, Wannan,et al. Study on the Morphologies of Covalent Organic Microporous Polymers: the Role of Reaction Solvents[J]. macromolecular chemistry and physics,2012,213(14):1435-1440. |
| APA | Tan, Dazhi.,Fan, Wenjie.,Xiong, Wannan.,Sun, Hanxue.,Cheng, Yaqi.,...&Deng, Wei-Qiao.(2012).Study on the Morphologies of Covalent Organic Microporous Polymers: the Role of Reaction Solvents.macromolecular chemistry and physics,213(14),1435-1440. |
| MLA | Tan, Dazhi,et al."Study on the Morphologies of Covalent Organic Microporous Polymers: the Role of Reaction Solvents".macromolecular chemistry and physics 213.14(2012):1435-1440. |
入库方式： OAI收割
来源：大连化学物理研究所
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