Preparation of Ce-modified Raney Ni Catalysts and Their Application in Aqueous-Phase Reforming of Cellulose
文献类型：期刊论文
| 作者 | Wen, Guodong1; Xu, Yunpeng1; Liu, Qianhe1,2; Wang, Congxin1,2; Liu, Hao1,2; Tian, Zhijian1,3 |
| 刊名 | catalysis letters
 |
| 出版日期 | 2011-12-01 |
| 卷号 | 141期号:12页码:1851-1858 |
| 关键词 | Aqueous-phase reforming Cellulose Hydrogen Raney Ni catalyst Ce |
| ISSN号 | 1011-372x |
| 产权排序 | 1,1 |
| 通讯作者 | 温国栋 |
| 英文摘要 | a series of ce-modified raney ni (rni) catalysts were successfully prepared by a simple wet chemical route and employed in aqueous-phase reforming of cellulose. remarkable enhancement in hydrogen selectivity and yield after the ce introduction was observed. at 533 k and autogenous pressure, a highest hydrogen yield of 17.8 mmol/g(cellulose), which was comparable with that of 5 wt% pt/ac, could be obtained over ce-modified catalyst at a ce:ni ratio of 0.054. the catalysts were characterized by n-2 adsorption/desorption, xrd, sem, xps and h-2-tpd. it was found that cerium existed at the surface of the catalyst as ce(oh)(3), and more defects were generated during ce modification. based on the characterization and catalytic performance, it was suggested that the deposited ce(oh)(3) may transform into reducible ceo2 under the reaction conditions, thus promoting the desired water-gas shift reaction, leading to more h-2. on the other hand, the active sites for undesired methanation reaction may be effectively poisoned by ce modification, thus leading to less undesired methane. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | biomass-derived hydrocarbons ; ethylene-glycol ; hydrogen-production ; xps ; surfaces ; glucose ; metal ; water ; co ; reduction |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000299919300017 |
| 公开日期 | 2013-10-11 |
| 源URL | [http://159.226.238.44/handle/321008/118537]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wen, Guodong,Xu, Yunpeng,Liu, Qianhe,et al. Preparation of Ce-modified Raney Ni Catalysts and Their Application in Aqueous-Phase Reforming of Cellulose[J]. catalysis letters,2011,141(12):1851-1858. |
| APA | Wen, Guodong,Xu, Yunpeng,Liu, Qianhe,Wang, Congxin,Liu, Hao,&Tian, Zhijian.(2011).Preparation of Ce-modified Raney Ni Catalysts and Their Application in Aqueous-Phase Reforming of Cellulose.catalysis letters,141(12),1851-1858. |
| MLA | Wen, Guodong,et al."Preparation of Ce-modified Raney Ni Catalysts and Their Application in Aqueous-Phase Reforming of Cellulose".catalysis letters 141.12(2011):1851-1858. |
入库方式： OAI收割
来源：大连化学物理研究所
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