Radical C-H Sulfonation of Arenes: Its Applications on Bioactive and DNA-Encoded Molecules
文献类型：期刊论文
| 作者 | Zhang, Yue4; Xia, Shengdi1,2,3; Shi, Wen-xia4; Lin, Bizhen4; Su, Xiao-can4; Lu, Weiwei2,3; Wu, Xinyuan2,3; Wang, Xuan2,3; Lu, Xiaojie2,3 ; Yan, Ming4
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| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2022-10-24 |
| 页码 | 6 |
| ISSN号 | 1523-7060 |
| DOI | 10.1021/acs.orglett.2c03077 |
| 通讯作者 | Zhang, Xue-jing(zhangxj33@mail.sysu.edu.cn) |
| 英文摘要 | The photocatalyst-free electron donor-acceptor (EDA) complex photochemistry was deemed to expand the potential of photodriven radical chemistry. Here, we report a cross-coupling reaction of thianthrenium salt functionalized arenes and sodium sulfinates via a photopromoted single electron transfer (SET) process of an EDA complex. A series of biarylsulfones were obtained with high site-selectivity and reactivity. This mild and practical radical reaction could be applied on the bioactive and DNA encoded molecules. |
| WOS关键词 | CHEMICAL LIBRARIES ; ALKYLATION ; REGULATOR ; STRATEGY |
| 资助项目 | National Natural Science Foundation of China[82061128001] ; Natural Science Foundation of Guangdong[2021A1515010503] ; Natural Science Foundation of Guangdong[2021A1515010186] ; Natural Science Foundation of Guangdong[2022A1515010744] ; Fundamental Research Funds for the Central Universities, Sun Yat-sen University[2021qntd44] ; Guangdong Provincial Key Laboratory of Chiral Molecules and Drug Discovery[2019B030301005] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000877103500001 |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/303008]  |
| 专题 | 新药研究国家重点实验室 |
| 通讯作者 | Zhang, Xue-jing |
| 作者单位 | 1.Nanjing Univ Chinese Med, Sch Chinese Mat Med, Nanjing 210023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Mat Med, State Key Lab Drug Res, Shanghai 201203, Peoples R China 4.Sun Yat sen Univ, Sch Pharmaceut Sci, Guangdong Prov Key Lab Chiral Mol & Drug Discovery, Guangzhou 510006, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Yue,Xia, Shengdi,Shi, Wen-xia,et al. Radical C-H Sulfonation of Arenes: Its Applications on Bioactive and DNA-Encoded Molecules[J]. ORGANIC LETTERS,2022:6. |
| APA | Zhang, Yue.,Xia, Shengdi.,Shi, Wen-xia.,Lin, Bizhen.,Su, Xiao-can.,...&Zhang, Xue-jing.(2022).Radical C-H Sulfonation of Arenes: Its Applications on Bioactive and DNA-Encoded Molecules.ORGANIC LETTERS,6. |
| MLA | Zhang, Yue,et al."Radical C-H Sulfonation of Arenes: Its Applications on Bioactive and DNA-Encoded Molecules".ORGANIC LETTERS (2022):6. |
入库方式： OAI收割
来源：上海药物研究所
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