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  4. 中科院海岸带环境过程与生态修复重点实验室
Selective cationic covalent organic framework for high throughput rapid extraction of novel polyfluoroalkyl substances

文献类型：期刊论文

作者Li, Shuang4; Ma, Jiping4; Guan, Jing4; Li, Jinhua2,3; Wang, Xiaoyan1; Sun, Xiyan3; Chen, Lingxin2,3
刊名JOURNAL OF HAZARDOUS MATERIALS
出版日期2023-01-15
卷号442页码:11
ISSN号0304-3894
关键词Novel per and polyfluoroalkyl substances (PFASs) Cationic covalent organic frameworks (iCOFs) Solid -phase extraction (SPE) UHPLC -MS MS Water samples
DOI10.1016/j.jhazmat.2022.130125
通讯作者Ma, Jiping(majiping2012@163.com) ; Chen, Lingxin(lxchen@yic.ac.cn)
英文摘要Novel per-and polyfluoroalkyl substances (PFASs) raise global concerns due to their toxic effects on environment and human health. However, researches on analytical methods of novel PFASs are lacking. Here, a kind of se-lective cationic covalent organic framework (iCOF) was designed and loaded on the surface of cotton as an adsorbent. Then, a simple solid-phase extraction (SPE) method based on the cotton@iCOF was developed for high throughput rapid extraction of six novel PFASs in water samples, coupled with ultrahigh-performance liquid chromatography-tandem mass spectrometry (UHPLC-MS/MS) determination. Several important SPE parame-ters, such as the amount of iCOF, sample pH, desorption conditions and salinity were systematically investigated. Under optimal conditions, the limits of detection and quantification of this SPE-UHPLC-MS/MS method were as low as 0.08-2.14 ng/L and 0.28-7.15 ng/L, respectively. The recoveries were 77.9-117.6 % for the tap water and surface water, and F-53 B in surface water were detected. Notably, this SPE process was rapid (1 h for 500 mL water sample) compared with commercial SPE (normal 2-3 h), owing to little resistance of cotton@iCOF and omission of nitrogen blowing process, and high throughput with 12 samples concurrently extracted. Addition-ally, various characterization means and density functional theory (DFT) calculations showed that ion-exchange effect, hydrophobic interaction, hydrogen bonding and ordered channel structure synergistically contributed to the PFASs adsorption on cotton@iCOF. The cotton@iCOF-based SPE method with simplicity, rapidity, selectivity and efficiency provided new research ideas for the analysis and control of ionic emerging pollutants in water.
WOS关键词FLUORINATED ALTERNATIVES ; METAL ; CRYSTALLINE ; SULFONATES ; HEALTH ; LEGACY ; WATER ; ACIDS
WOS研究方向Engineering ; Environmental Sciences & Ecology
语种英语
WOS记录号WOS:000890545900002
资助机构National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Natural Science Foundation of Shandong Province of China ; Taishan Scholar Project Special Funding
源URL[http://ir.yic.ac.cn/handle/133337/31903]  
专题烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室
烟台海岸带研究所_山东省海岸带环境工程技术研究中心
通讯作者Ma, Jiping; Chen, Lingxin
作者单位1.Binzhou Med Univ, Sch Pharm, Yantai 264003, Peoples R China
2.Pilot Natl Lab Marine Sci & Technol, Lab Marine Biol & Biotechnol, Qingdao 266237, Peoples R China
3.Chinese Acad Sci, Yantai Inst Coastal Zone Res, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Shandong Key Lab Coastal Environm Proc, Yantai 264003, Peoples R China
4.Qingdao Univ Technol, Sch Environm & Municipal Engn, Qingdao 266033, Peoples R China
推荐引用方式
GB/T 7714		 Li, Shuang,Ma, Jiping,Guan, Jing,et al. Selective cationic covalent organic framework for high throughput rapid extraction of novel polyfluoroalkyl substances[J]. JOURNAL OF HAZARDOUS MATERIALS,2023,442:11.
APA Li, Shuang.,Ma, Jiping.,Guan, Jing.,Li, Jinhua.,Wang, Xiaoyan.,...&Chen, Lingxin.(2023).Selective cationic covalent organic framework for high throughput rapid extraction of novel polyfluoroalkyl substances.JOURNAL OF HAZARDOUS MATERIALS,442,11.
MLA Li, Shuang,et al."Selective cationic covalent organic framework for high throughput rapid extraction of novel polyfluoroalkyl substances".JOURNAL OF HAZARDOUS MATERIALS 442(2023):11.

入库方式： OAI收割

来源：烟台海岸带研究所

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