Conservation of the Stokes-Einstein relation in supercooled water
文献类型：期刊论文
| 作者 | Ren, Gan; Wang, Yanting1,2
|
| 刊名 | PHYSICAL CHEMISTRY CHEMICAL PHYSICS
 |
| 出版日期 | 2021 |
| 卷号 | 23期号:43页码:24541-24544 |
| ISSN号 | 1463-9076 |
| 关键词 | DYNAMICS TEMPERATURE VISCOSITY TRANSITION DIFFUSION BREAKDOWN LIQUIDS GROMACS MODEL |
| DOI | 10.1039/d1cp03972e |
| 英文摘要 | The Stokes-Einstein (SE) relation is commonly regarded as being breakdown in supercooled water. However, this conclusion is drawn by testing the validity of some variants of the SE relation rather than its original form, and it appears conflicting with the fact that supercooled water is in its local equilibrium. In this work, we show by molecular dynamics simulations that the Stokes-Einstein relation is indeed conserved in supercooled water. The inconsistency between the original SE relation and its variants comes from two facts: (1) the substitutes of the shear viscosity in the SE variants are only approximate relations; and (2) the effective hydrodynamic radius actually decreases with decreasing temperature, instead of being a constant as assumed in the SE variants. |
| 学科主题 | Chemistry ; Physics |
| 语种 | 英语 |
| 源URL | [http://ir.itp.ac.cn/handle/311006/27599]  |
| 专题 | 理论物理研究所_理论物理所1978-2010年知识产出 |
| 作者单位 | 1.Civil Aviat Flight Univ China, Sch Sci, Guanghan 628307, Peoples R China 2.Chinese Acad Sci, Inst Theoret Phys, CAS Key Lab Theoret Phys, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Sch Phys Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ren, Gan,Wang, Yanting. Conservation of the Stokes-Einstein relation in supercooled water[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2021,23(43):24541-24544. |
| APA | Ren, Gan,&Wang, Yanting.(2021).Conservation of the Stokes-Einstein relation in supercooled water.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,23(43),24541-24544. |
| MLA | Ren, Gan,et al."Conservation of the Stokes-Einstein relation in supercooled water".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 23.43(2021):24541-24544. |
入库方式： OAI收割
来源：理论物理研究所
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