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Progress of vanadium phosphorous oxide catalyst for n-butane selective oxidation

文献类型：期刊论文

作者Faizan, Muhammad1,2; Li, Yingwei1,2; Zhang, Ruirui1; Wang, Xingsheng1; Song, Piao1,2; Liu, Ruixia1,2
刊名CHINESE JOURNAL OF CHEMICAL ENGINEERING
出版日期2022-03-01
卷号43页码:297-315
ISSN号1004-9541
关键词N-butane selective oxidation Oxidation of light alkanes Vanadium phosphorus oxide (VPO) Maleic anhydride
DOI10.1016/j.cjche.2021.10.026
英文摘要The utilization of lighter alkanes into useful chemical products is essential for modern chemistry and reducing the CO2 emission. Particularly, n-butane has gained special attention across the globe due to the abundant production of maleic anhydride (MA). Vanadium phosphorous oxide (VPO) is the most effective catalyst for selective oxidation of n-butane to MA so far. Interestingly, the VPO complex exists in more or less fifteen different structures, each one having distinct phase composition and exclusive surface morphology and physiochemical properties such as valence state, lattice oxygen, acidity etc., which relies on precursor preparation method and the activation conditions of catalysts. The catalytic performance of VPO catalyst is improved by adding different promoters or co-catalyst such as various metals dopants, or either introducing template or structural-directing agents. Meanwhile, new preparation strategies such as electrospinning, ball milling, hydrothermal, barothermal, ultrasound, microwave irradiation, calcination, sol-gel method and solvothermal synthesis are also employed for introducing improvement in catalytic performance. Research in above-mentioned different aspects will be ascribed in current review in addition to summarizing overall catalysis activity and final yield. To analyze the performance of the catalytic precursor, the reaction mechanism and reaction kinetics both are discussed in this review to help clarify the key issues such as strong exothermic reaction, phosphorus supplement, water supplement, deactivation, and air/n-butane pretreatment etc. related to the various industrial applications of VPO. (c) 2021 The Chemical Industry and Engineering Society of China, and Chemical Industry Press Co., Ltd. All rights reserved.
资助项目National Key Research and Development Program of China[2017YFA0206803] ; innovation Academy for Green Manufacture of Chinese Academy of Science[IAGM2020C17] ; Key Programs of the Chinese Academy of Sciences[KFZD-SW-413] ; National Nature Science Foundation of China[21808223] ; Key Programs of Fujian Institute of Innovation, CAS, Chinese Academy of Sciences[FJCXY18020203] ; One Hundred Talent Program of CAS
WOS研究方向Engineering
语种英语
出版者CHEMICAL INDUSTRY PRESS CO LTD
WOS记录号WOS:000788278900001
资助机构National Key Research and Development Program of China ; innovation Academy for Green Manufacture of Chinese Academy of Science ; Key Programs of the Chinese Academy of Sciences ; National Nature Science Foundation of China ; Key Programs of Fujian Institute of Innovation, CAS, Chinese Academy of Sciences ; One Hundred Talent Program of CAS
源URL[http://ir.ipe.ac.cn/handle/122111/53264]  
专题中国科学院过程工程研究所
通讯作者Liu, Ruixia
作者单位1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ionic Liquids Clean Proc, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714		 Faizan, Muhammad,Li, Yingwei,Zhang, Ruirui,et al. Progress of vanadium phosphorous oxide catalyst for n-butane selective oxidation[J]. CHINESE JOURNAL OF CHEMICAL ENGINEERING,2022,43:297-315.
APA Faizan, Muhammad,Li, Yingwei,Zhang, Ruirui,Wang, Xingsheng,Song, Piao,&Liu, Ruixia.(2022).Progress of vanadium phosphorous oxide catalyst for n-butane selective oxidation.CHINESE JOURNAL OF CHEMICAL ENGINEERING,43,297-315.
MLA Faizan, Muhammad,et al."Progress of vanadium phosphorous oxide catalyst for n-butane selective oxidation".CHINESE JOURNAL OF CHEMICAL ENGINEERING 43(2022):297-315.

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来源：过程工程研究所

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